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result sql = Determination of dissolved sulphides in waste water samples by flow-through stripping chronopotentiometry with a macroporous mercury-film electrode.
Determination of dissolved sulphides in waste water samples by flow-through stripping chronopotentiometry with a macroporous mercury-film electrode.
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char = e;code = 101
char = r;code = 114
char = ;code = 32
char = s;code = 115
char = a;code = 97
char = m;code = 109
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = f;code = 102
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = t;code = 116
char = a;code = 97
char = n;code = 110
char = n;code = 110
char = e;code = 101
char = r;code = 114
char = y;code = 121
char = .;code = 46
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
result sql = Sulphides in water samples were determined by stripping chronopotentiometry in a computer controlled flow system with a flow-through electrochemical cell. The working electrode was a porous glassy carbon electrode coated with Nafion and mercury. The sample was diluted with 0.1 mol L(-1) NaOH and analysed. Sulphides in the sample were collected in the porous electrode as mercury sulphide and then stripped by a current of -500 microA. The limit of detection was found to be 1.6 microg L(-1) and 0.5 microg L(-1) for 1 mL and 5 mL of preconcentrated sample, respectively. The linear range for 1mL sample was found to be 5-400 microg L(-1). The repeatability and reproducibility was found to be 2.6% and 4.8%, respectively. The method was applied to analyses of waste water samples from a tannery.

Publication: Anal. Chim. Acta 2007 Apr 4 ;588(1)::16-9.
Publication Date: 2007 Apr 4
Study Author(s): Manova, A;Strelec, M;Cacho, F;Lehotay, J;Beinrohr, E;
Institution: Slovak University of Technology, Institute of Analytical Chemistry, Radlinskeho 9, 812 37 Bratislava, Slovakia.
Shortcut link to this study:
Sulphides in water samples were determined by stripping chronopotentiometry in a computer controlled flow system with a flow-through electrochemical cell. The working electrode was a porous glassy carbon electrode coated with Nafion and mercury. The sample was diluted with 0.1 mol L(-1) NaOH and analysed. Sulphides in the sample were collected in the porous electrode as mercury sulphide and then stripped by a current of -500 microA. The limit of detection was found to be 1.6 microg L(-1) and 0.5 microg L(-1) for 1 mL and 5 mL of preconcentrated sample, respectively. The linear range for 1mL sample was found to be 5-400 microg L(-1). The repeatability and reproducibility was found to be 2.6% and 4.8%, respectively. The method was applied to analyses of waste water samples from a tannery.
PMID: 17386788

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