|
|
char = N;code = 78
char = i;code = 105
char = c;code = 99
char = k;code = 107
char = e;code = 101
char = l;code = 108
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = e;code = 101
char = n;code = 110
char = c;code = 99
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = .;code = 46
result sql = Nickel sorption to goethite and montmorillonite in presence of citrate.
Nickel sorption to goethite and montmorillonite in presence of citrate.char = M;code = 77
char = o;code = 111
char = b;code = 98
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = t;code = 116
char = y;code = 121
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = i;code = 105
char = o;code = 111
char = a;code = 97
char = v;code = 118
char = a;code = 97
char = i;code = 105
char = l;code = 108
char = a;code = 97
char = b;code = 98
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = t;code = 116
char = y;code = 121
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = n;code = 110
char = i;code = 105
char = c;code = 99
char = k;code = 107
char = e;code = 101
char = l;code = 108
char = ;code = 32
char = (;code = 40
char = N;code = 78
char = i;code = 105
char = );code = 41
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = i;code = 105
char = l;code = 108
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = g;code = 103
char = l;code = 108
char = y;code = 121
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = p;code = 112
char = e;code = 101
char = n;code = 110
char = d;code = 100
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = t;code = 116
char = w;code = 119
char = e;code = 101
char = e;code = 101
char = n;code = 110
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = ,;code = 44
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = b;code = 98
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = s;code = 115
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = k;code = 107
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = r;code = 114
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = m;code = 109
char = a;code = 97
char = t;code = 116
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = l;code = 108
char = s;code = 115
char = .;code = 46
char = ;code = 32
char = S;code = 83
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = -;code = 45
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = m;code = 109
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = x;code = 120
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = a;code = 97
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = b;code = 98
char = a;code = 97
char = t;code = 116
char = c;code = 99
char = h;code = 104
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = i;code = 105
char = m;code = 109
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = s;code = 115
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = o;code = 111
char = u;code = 117
char = t;code = 116
char = ;code = 32
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = H;code = 72
char = ;code = 32
char = r;code = 114
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = H;code = 72
char = ;code = 32
char = 4;code = 52
char = -;code = 45
char = 7;code = 55
char = .;code = 46
char = 5;code = 53
char = .;code = 46
char = ;code = 32
char = W;code = 87
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = o;code = 111
char = u;code = 117
char = t;code = 116
char = ;code = 32
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ,;code = 44
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = h;code = 104
char = o;code = 111
char = w;code = 119
char = s;code = 115
char = ;code = 32
char = h;code = 104
char = i;code = 105
char = g;code = 103
char = h;code = 104
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = .;code = 46
char = ;code = 32
char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = g;code = 103
char = l;code = 108
char = y;code = 121
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = c;code = 99
char = r;code = 114
char = e;code = 101
char = a;code = 97
char = s;code = 115
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;;code = 59
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = e;code = 101
char = n;code = 110
char = c;code = 99
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = 1;code = 49
char = 0;code = 48
char = 0;code = 48
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = c;code = 99
char = r;code = 114
char = o;code = 111
char = M;code = 77
char = ;code = 32
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = c;code = 99
char = o;code = 111
char = m;code = 109
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = b;code = 98
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = .;code = 46
char = ;code = 32
char = <;code = 60
char = b;code = 98
char = >;code = 62
char = N;code = 78
char = I;code = 73
char = ;code = 32
char = A;code = 65
char = N;code = 78
char = D;code = 68
char = ;code = 32
char = C;code = 67
char = I;code = 73
char = T;code = 84
char = R;code = 82
char = A;code = 65
char = T;code = 84
char = E;code = 69
char = ;code = 32
char = S;code = 83
char = O;code = 79
char = R;code = 82
char = P;code = 80
char = T;code = 84
char = I;code = 73
char = O;code = 79
char = N;code = 78
char = ;code = 32
char = W;code = 87
char = A;code = 65
char = S;code = 83
char = ;code = 32
char = M;code = 77
char = O;code = 79
char = D;code = 68
char = E;code = 69
char = L;code = 76
char = E;code = 69
char = D;code = 68
char = ;code = 32
char = S;code = 83
char = U;code = 85
char = C;code = 67
char = C;code = 67
char = E;code = 69
char = S;code = 83
char = S;code = 83
char = F;code = 70
char = U;code = 85
char = L;code = 76
char = L;code = 76
char = Y;code = 89
char = ;code = 32
char = U;code = 85
char = S;code = 83
char = I;code = 73
char = N;code = 78
char = G;code = 71
char = ;code = 32
char = T;code = 84
char = H;code = 72
char = E;code = 69
char = ;code = 32
char = D;code = 68
char = I;code = 73
char = F;code = 70
char = F;code = 70
char = U;code = 85
char = S;code = 83
char = E;code = 69
char = ;code = 32
char = D;code = 68
char = O;code = 79
char = U;code = 85
char = B;code = 66
char = L;code = 76
char = E;code = 69
char = ;code = 32
char = L;code = 76
char = A;code = 65
char = Y;code = 89
char = E;code = 69
char = R;code = 82
char = ;code = 32
char = M;code = 77
char = O;code = 79
char = D;code = 68
char = E;code = 69
char = L;code = 76
char = ;code = 32
char = W;code = 87
char = I;code = 73
char = T;code = 84
char = H;code = 72
char = ;code = 32
char = T;code = 84
char = H;code = 72
char = E;code = 69
char = ;code = 32
char = F;code = 70
char = O;code = 79
char = L;code = 76
char = L;code = 76
char = O;code = 79
char = W;code = 87
char = I;code = 73
char = N;code = 78
char = G;code = 71
char = ;code = 32
char = R;code = 82
char = E;code = 69
char = A;code = 65
char = C;code = 67
char = T;code = 84
char = I;code = 73
char = O;code = 79
char = N;code = 78
char = S;code = 83
char = :;code = 58
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
char = <;code = 60
char = b;code = 98
char = >;code = 62
char = G;code = 71
char = O;code = 79
char = E;code = 69
char = T;code = 84
char = H;code = 72
char = I;code = 73
char = T;code = 84
char = E;code = 69
char = :;code = 58
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = 3;code = 51
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = F;code = 70
char = e;code = 101
char = O;code = 79
char = H;code = 72
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = (;code = 40
char = 3;code = 51
char = -;code = 45
char = );code = 41
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = 3;code = 51
char = H;code = 72
char = +;code = 43
char = ;code = 32
char = <;code = 60
char = =;code = 61
char = >;code = 62
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = ;code = 32
char = F;code = 70
char = e;code = 101
char = 3;code = 51
char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = 3;code = 51
char = H;code = 72
char = 2;code = 50
char = O;code = 79
char = ,;code = 44
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = F;code = 70
char = e;code = 101
char = O;code = 79
char = H;code = 72
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = 2;code = 50
char = +;code = 43
char = ;code = 32
char = <;code = 60
char = =;code = 61
char = >;code = 62
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = ;code = 32
char = F;code = 70
char = e;code = 101
char = O;code = 79
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = H;code = 72
char = +;code = 43
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = 2;code = 50
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char = +;code = 43
char = ;code = 32
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char = +;code = 43
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char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
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char = i;code = 105
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = a;code = 97
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char = t;code = 116
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char = f;code = 102
char = ;code = 32
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char = o;code = 111
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char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
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char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = u;code = 117
char = l;code = 108
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = l;code = 108
char = c;code = 99
char = u;code = 117
char = l;code = 108
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char = t;code = 116
char = e;code = 101
char = d;code = 100
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char = b;code = 98
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char = ;code = 32
char = u;code = 117
char = s;code = 115
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
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char = s;code = 115
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char = n;code = 110
char = d;code = 100
char = ;code = 32
char = c;code = 99
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char = a;code = 97
char = n;code = 110
char = t;code = 116
char = s;code = 115
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char = o;code = 111
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char = t;code = 116
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char = t;code = 116
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char = h;code = 104
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = b;code = 98
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = a;code = 97
char = m;code = 109
char = o;code = 111
char = u;code = 117
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = m;code = 109
char = a;code = 97
char = s;code = 115
char = s;code = 115
char = ;code = 32
char = u;code = 117
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = m;code = 109
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char = x;code = 120
char = t;code = 116
char = u;code = 117
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char = ;code = 32
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char = ;code = 32
char = b;code = 98
char = e;code = 101
char = ;code = 32
char = f;code = 102
char = o;code = 111
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char = n;code = 110
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char = ;code = 32
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char = m;code = 109
char = p;code = 112
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char = r;code = 114
char = a;code = 97
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char = f;code = 102
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char = i;code = 105
char = o;code = 111
char = n;code = 110
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char = o;code = 111
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = t;code = 116
char = w;code = 119
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char = e;code = 101
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char = p;code = 112
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char = e;code = 101
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char = p;code = 112
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char = i;code = 105
char = o;code = 111
char = n;code = 110
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char = t;code = 116
char = o;code = 111
char = ;code = 32
char = g;code = 103
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result sql = Mobility and bioavailability of nickel (Ni) in soil strongly depends on the interaction between Ni(II), ligands, and sorbents like organic matter and minerals. Sorption of Ni(II) and Ni(II)-citrate complexes to goethite and montmorillonite was examined in batch experiments with and without citrate as ligand in the pH range pH 4-7.5. Without citrate, montmorillonite shows higher Ni sorption than goethite. Citrate strongly decreases Ni sorption to montmorillonite; in presence of 100 microM citrate goethite becomes a stronger Ni sorbent than montmorillonite. NI AND CITRATE SORPTION WAS MODELED SUCCESSFULLY USING THE DIFFUSE DOUBLE LAYER MODEL WITH THE FOLLOWING REACTIONS:
GOETHITE: 3 [triple bond]FeOH + Citrate(3-) + 3H+ <=> [triple bond] Fe3Citrate + 3H2O, [triple bond]FeOH + Ni2+ <=> [triple bond] FeONi + H+ and 2 [triple bond] FeOH + Citrate(3)- + Ni2+ <=> [triple bond] FeONiCitrate(2-) + H+.
MONTMORILLONITE: 2X- + Ni2+ <=> X2Ni and [triple bond] AIOH + Ni2+ <=> AIONi+ + H+. Sorption of Ni to a mixture of goethite and montmorillonite could be calculated by use of reactions and constants for the monomineral systems. Without citrate, the sorbed amount of Ni per mass unit in the mixture can be found as a simple average of sorption to the two single sorbents, while in presence of citrate Ni sorption to montmorillonite is strongly influenced by citrate sorption to goethite.
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char = k;code = 107
char = e;code = 101
char = l;code = 108
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
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char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
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char = i;code = 105
char = n;code = 110
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = e;code = 101
char = n;code = 110
char = c;code = 99
char = e;code = 101
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result sql = Nickel sorption to goethite and montmorillonite in presence of citrate.
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char = e;code = 101
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = a;code = 97
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = b;code = 98
char = a;code = 97
char = t;code = 116
char = c;code = 99
char = h;code = 104
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = i;code = 105
char = m;code = 109
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = s;code = 115
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = o;code = 111
char = u;code = 117
char = t;code = 116
char = ;code = 32
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = H;code = 72
char = ;code = 32
char = r;code = 114
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = H;code = 72
char = ;code = 32
char = 4;code = 52
char = -;code = 45
char = 7;code = 55
char = .;code = 46
char = 5;code = 53
char = .;code = 46
char = ;code = 32
char = W;code = 87
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = o;code = 111
char = u;code = 117
char = t;code = 116
char = ;code = 32
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ,;code = 44
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = h;code = 104
char = o;code = 111
char = w;code = 119
char = s;code = 115
char = ;code = 32
char = h;code = 104
char = i;code = 105
char = g;code = 103
char = h;code = 104
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = .;code = 46
char = ;code = 32
char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = g;code = 103
char = l;code = 108
char = y;code = 121
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = c;code = 99
char = r;code = 114
char = e;code = 101
char = a;code = 97
char = s;code = 115
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;;code = 59
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = e;code = 101
char = n;code = 110
char = c;code = 99
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = 1;code = 49
char = 0;code = 48
char = 0;code = 48
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = c;code = 99
char = r;code = 114
char = o;code = 111
char = M;code = 77
char = ;code = 32
char = c;code = 99
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = c;code = 99
char = o;code = 111
char = m;code = 109
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = b;code = 98
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = .;code = 46
char = ;code = 32
char = <;code = 60
char = b;code = 98
char = >;code = 62
char = N;code = 78
char = I;code = 73
char = ;code = 32
char = A;code = 65
char = N;code = 78
char = D;code = 68
char = ;code = 32
char = C;code = 67
char = I;code = 73
char = T;code = 84
char = R;code = 82
char = A;code = 65
char = T;code = 84
char = E;code = 69
char = ;code = 32
char = S;code = 83
char = O;code = 79
char = R;code = 82
char = P;code = 80
char = T;code = 84
char = I;code = 73
char = O;code = 79
char = N;code = 78
char = ;code = 32
char = W;code = 87
char = A;code = 65
char = S;code = 83
char = ;code = 32
char = M;code = 77
char = O;code = 79
char = D;code = 68
char = E;code = 69
char = L;code = 76
char = E;code = 69
char = D;code = 68
char = ;code = 32
char = S;code = 83
char = U;code = 85
char = C;code = 67
char = C;code = 67
char = E;code = 69
char = S;code = 83
char = S;code = 83
char = F;code = 70
char = U;code = 85
char = L;code = 76
char = L;code = 76
char = Y;code = 89
char = ;code = 32
char = U;code = 85
char = S;code = 83
char = I;code = 73
char = N;code = 78
char = G;code = 71
char = ;code = 32
char = T;code = 84
char = H;code = 72
char = E;code = 69
char = ;code = 32
char = D;code = 68
char = I;code = 73
char = F;code = 70
char = F;code = 70
char = U;code = 85
char = S;code = 83
char = E;code = 69
char = ;code = 32
char = D;code = 68
char = O;code = 79
char = U;code = 85
char = B;code = 66
char = L;code = 76
char = E;code = 69
char = ;code = 32
char = L;code = 76
char = A;code = 65
char = Y;code = 89
char = E;code = 69
char = R;code = 82
char = ;code = 32
char = M;code = 77
char = O;code = 79
char = D;code = 68
char = E;code = 69
char = L;code = 76
char = ;code = 32
char = W;code = 87
char = I;code = 73
char = T;code = 84
char = H;code = 72
char = ;code = 32
char = T;code = 84
char = H;code = 72
char = E;code = 69
char = ;code = 32
char = F;code = 70
char = O;code = 79
char = L;code = 76
char = L;code = 76
char = O;code = 79
char = W;code = 87
char = I;code = 73
char = N;code = 78
char = G;code = 71
char = ;code = 32
char = R;code = 82
char = E;code = 69
char = A;code = 65
char = C;code = 67
char = T;code = 84
char = I;code = 73
char = O;code = 79
char = N;code = 78
char = S;code = 83
char = :;code = 58
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
char = <;code = 60
char = b;code = 98
char = >;code = 62
char = G;code = 71
char = O;code = 79
char = E;code = 69
char = T;code = 84
char = H;code = 72
char = I;code = 73
char = T;code = 84
char = E;code = 69
char = :;code = 58
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = 3;code = 51
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = F;code = 70
char = e;code = 101
char = O;code = 79
char = H;code = 72
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = (;code = 40
char = 3;code = 51
char = -;code = 45
char = );code = 41
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = 3;code = 51
char = H;code = 72
char = +;code = 43
char = ;code = 32
char = <;code = 60
char = =;code = 61
char = >;code = 62
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = ;code = 32
char = F;code = 70
char = e;code = 101
char = 3;code = 51
char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = 3;code = 51
char = H;code = 72
char = 2;code = 50
char = O;code = 79
char = ,;code = 44
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = F;code = 70
char = e;code = 101
char = O;code = 79
char = H;code = 72
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = 2;code = 50
char = +;code = 43
char = ;code = 32
char = <;code = 60
char = =;code = 61
char = >;code = 62
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = ;code = 32
char = F;code = 70
char = e;code = 101
char = O;code = 79
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = H;code = 72
char = +;code = 43
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = 2;code = 50
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = ;code = 32
char = F;code = 70
char = e;code = 101
char = O;code = 79
char = H;code = 72
char = ;code = 32
char = +;code = 43
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char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = (;code = 40
char = 3;code = 51
char = );code = 41
char = -;code = 45
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = 2;code = 50
char = +;code = 43
char = ;code = 32
char = <;code = 60
char = =;code = 61
char = >;code = 62
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
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char = i;code = 105
char = C;code = 67
char = i;code = 105
char = t;code = 116
char = r;code = 114
char = a;code = 97
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char = e;code = 101
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char = 2;code = 50
char = -;code = 45
char = );code = 41
char = ;code = 32
char = +;code = 43
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char = H;code = 72
char = +;code = 43
char = .;code = 46
char = ;code = 32
char = <;code = 60
char = b;code = 98
char = r;code = 114
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char = >;code = 62
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
char = <;code = 60
char = b;code = 98
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char = M;code = 77
char = O;code = 79
char = N;code = 78
char = T;code = 84
char = M;code = 77
char = O;code = 79
char = R;code = 82
char = I;code = 73
char = L;code = 76
char = L;code = 76
char = O;code = 79
char = N;code = 78
char = I;code = 73
char = T;code = 84
char = E;code = 69
char = :;code = 58
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = 2;code = 50
char = X;code = 88
char = -;code = 45
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = 2;code = 50
char = +;code = 43
char = ;code = 32
char = <;code = 60
char = =;code = 61
char = >;code = 62
char = ;code = 32
char = X;code = 88
char = 2;code = 50
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = [;code = 91
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ];code = 93
char = ;code = 32
char = A;code = 65
char = I;code = 73
char = O;code = 79
char = H;code = 72
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = 2;code = 50
char = +;code = 43
char = ;code = 32
char = <;code = 60
char = =;code = 61
char = >;code = 62
char = ;code = 32
char = A;code = 65
char = I;code = 73
char = O;code = 79
char = N;code = 78
char = i;code = 105
char = +;code = 43
char = ;code = 32
char = +;code = 43
char = ;code = 32
char = H;code = 72
char = +;code = 43
char = .;code = 46
char = ;code = 32
char = S;code = 83
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = N;code = 78
char = i;code = 105
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = x;code = 120
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = m;code = 109
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = l;code = 108
char = l;code = 108
char = o;code = 111
char = n;code = 110
char = i;code = 105
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = u;code = 117
char = l;code = 108
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = l;code = 108
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = u;code = 117
char = s;code = 115
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = n;code = 110
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result sql = Mobility and bioavailability of nickel (Ni) in soil strongly depends on the interaction between Ni(II), ligands, and sorbents like organic matter and minerals. Sorption of Ni(II) and Ni(II)-citrate complexes to goethite and montmorillonite was examined in batch experiments with and without citrate as ligand in the pH range pH 4-7.5. Without citrate, montmorillonite shows higher Ni sorption than goethite. Citrate strongly decreases Ni sorption to montmorillonite; in presence of 100 microM citrate goethite becomes a stronger Ni sorbent than montmorillonite. NI AND CITRATE SORPTION WAS MODELED SUCCESSFULLY USING THE DIFFUSE DOUBLE LAYER MODEL WITH THE FOLLOWING REACTIONS:
GOETHITE: 3 [triple bond]FeOH + Citrate(3-) + 3H+ <=> [triple bond] Fe3Citrate + 3H2O, [triple bond]FeOH + Ni2+ <=> [triple bond] FeONi + H+ and 2 [triple bond] FeOH + Citrate(3)- + Ni2+ <=> [triple bond] FeONiCitrate(2-) + H+.
MONTMORILLONITE: 2X- + Ni2+ <=> X2Ni and [triple bond] AIOH + Ni2+ <=> AIONi+ + H+. Sorption of Ni to a mixture of goethite and montmorillonite could be calculated by use of reactions and constants for the monomineral systems. Without citrate, the sorbed amount of Ni per mass unit in the mixture can be found as a simple average of sorption to the two single sorbents, while in presence of citrate Ni sorption to montmorillonite is strongly influenced by citrate sorption to goethite.
Publication: Environ. Sci. Technol. 2009 Feb 15 ;43(4)::1122-7.
Publication Date: 2009 Feb 15
Study Author(s): Marcussen, Helle;Holm, Peter E;Strobel, Bjarne W;Hansen, Hans Chr B;
Institution: Department of Basic Sciences and Environment, LIFE, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark. [email protected]
Shortcut link to this study:
Publication Date: 2009 Feb 15
Study Author(s): Marcussen, Helle;Holm, Peter E;Strobel, Bjarne W;Hansen, Hans Chr B;
Institution: Department of Basic Sciences and Environment, LIFE, University of Copenhagen, Thorvaldsensvej 40, DK-1871 Frederiksberg C, Denmark. [email protected]
Shortcut link to this study:
Mobility and bioavailability of nickel (Ni) in soil strongly depends on the interaction between Ni(II), ligands, and sorbents like organic matter and minerals. Sorption of Ni(II) and Ni(II)-citrate complexes to goethite and montmorillonite was examined in batch experiments with and without citrate as ligand in the pH range pH 4-7.5. Without citrate, montmorillonite shows higher Ni sorption than goethite. Citrate strongly decreases Ni sorption to montmorillonite; in presence of 100 microM citrate goethite becomes a stronger Ni sorbent than montmorillonite. NI AND CITRATE SORPTION WAS MODELED SUCCESSFULLY USING THE DIFFUSE DOUBLE LAYER MODEL WITH THE FOLLOWING REACTIONS:
GOETHITE: 3 [triple bond]FeOH + Citrate(3-) + 3H+ <=> [triple bond] Fe3Citrate + 3H2O, [triple bond]FeOH + Ni2+ <=> [triple bond] FeONi + H+ and 2 [triple bond] FeOH + Citrate(3)- + Ni2+ <=> [triple bond] FeONiCitrate(2-) + H+.
MONTMORILLONITE: 2X- + Ni2+ <=> X2Ni and [triple bond] AIOH + Ni2+ <=> AIONi+ + H+. Sorption of Ni to a mixture of goethite and montmorillonite could be calculated by use of reactions and constants for the monomineral systems. Without citrate, the sorbed amount of Ni per mass unit in the mixture can be found as a simple average of sorption to the two single sorbents, while in presence of citrate Ni sorption to montmorillonite is strongly influenced by citrate sorption to goethite.
GOETHITE: 3 [triple bond]FeOH + Citrate(3-) + 3H+ <=> [triple bond] Fe3Citrate + 3H2O, [triple bond]FeOH + Ni2+ <=> [triple bond] FeONi + H+ and 2 [triple bond] FeOH + Citrate(3)- + Ni2+ <=> [triple bond] FeONiCitrate(2-) + H+.
MONTMORILLONITE: 2X- + Ni2+ <=> X2Ni and [triple bond] AIOH + Ni2+ <=> AIONi+ + H+. Sorption of Ni to a mixture of goethite and montmorillonite could be calculated by use of reactions and constants for the monomineral systems. Without citrate, the sorbed amount of Ni per mass unit in the mixture can be found as a simple average of sorption to the two single sorbents, while in presence of citrate Ni sorption to montmorillonite is strongly influenced by citrate sorption to goethite.
PMID: 19320168
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