char = m;code = 109
char = u;code = 117
char = -;code = 45
char = O;code = 79
char = x;code = 120
char = o;code = 111
char = -;code = 45
char = b;code = 98
char = i;code = 105
char = s;code = 115
char = {;code = 123
char = [;code = 91
char = (;code = 40
char = 6;code = 54
char = -;code = 45
char = h;code = 104
char = y;code = 121
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = y;code = 121
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = -;code = 45
char = 2;code = 50
char = -;code = 45
char = p;code = 112
char = y;code = 121
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = y;code = 121
char = l;code = 108
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = );code = 41
char = b;code = 98
char = i;code = 105
char = s;code = 115
char = (;code = 40
char = 2;code = 50
char = -;code = 45
char = p;code = 112
char = y;code = 121
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = y;code = 121
char = l;code = 108
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = );code = 41
char = a;code = 97
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = -;code = 45
char = k;code = 107
char = a;code = 97
char = p;code = 112
char = p;code = 112
char = a;code = 97
char = );code = 41
char = N;code = 78
char = ,;code = 44
char = N;code = 78
char = ';code = 39
char = ,;code = 44
char = N;code = 78
char = ';code = 39
char = ';code = 39
char = ,;code = 44
char = N;code = 78
char = ';code = 39
char = ';code = 39
char = ';code = 39
char = ,;code = 44
char = O;code = 79
char = ];code = 93
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
char = );code = 41
char = };code = 125
char = ;code = 32
char = t;code = 116
char = e;code = 101
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = k;code = 107
char = i;code = 105
char = s;code = 115
char = (;code = 40
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = );code = 41
char = .;code = 46
result sql = mu-Oxo-bis{[(6-hydroxymethyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine-kappa)N,N',N'',N''',O]iron(III)} tetrakis(perchlorate).
mu-Oxo-bis{[(6-hydroxymethyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine-kappa)N,N',N'',N''',O]iron(III)} tetrakis(perchlorate).
char = T;code = 84
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = n;code = 110
char = o;code = 111
char = v;code = 118
char = e;code = 101
char = l;code = 108
char = ;code = 32
char = m;code = 109
char = u;code = 117
char = -;code = 45
char = o;code = 111
char = x;code = 120
char = o;code = 111
char = -;code = 45
char = d;code = 100
char = i;code = 105
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = m;code = 109
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = x;code = 120
char = ;code = 32
char = [;code = 91
char = F;code = 70
char = e;code = 101
char = 2;code = 50
char = O;code = 79
char = (;code = 40
char = B;code = 66
char = P;code = 80
char = H;code = 72
char = P;code = 80
char = A;code = 65
char = );code = 41
char = 2;code = 50
char = ];code = 93
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = 4;code = 52
char = );code = 41
char = 4;code = 52
char = ;code = 32
char = [;code = 91
char = B;code = 66
char = P;code = 80
char = H;code = 72
char = P;code = 80
char = A;code = 65
char = ;code = 32
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = (;code = 40
char = 6;code = 54
char = -;code = 45
char = h;code = 104
char = y;code = 121
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = y;code = 121
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = -;code = 45
char = 2;code = 50
char = -;code = 45
char = p;code = 112
char = y;code = 121
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = y;code = 121
char = l;code = 108
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = );code = 41
char = b;code = 98
char = i;code = 105
char = s;code = 115
char = (;code = 40
char = 2;code = 50
char = -;code = 45
char = p;code = 112
char = y;code = 121
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = y;code = 121
char = l;code = 108
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = );code = 41
char = a;code = 97
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ,;code = 44
char = ;code = 32
char = C;code = 67
char = 1;code = 49
char = 9;code = 57
char = H;code = 72
char = 2;code = 50
char = 0;code = 48
char = N;code = 78
char = 4;code = 52
char = O;code = 79
char = ];code = 93
char = ,;code = 44
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = t;code = 116
char = a;code = 97
char = i;code = 105
char = n;code = 110
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = b;code = 98
char = i;code = 105
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = s;code = 115
char = y;code = 121
char = m;code = 109
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = [;code = 91
char = F;code = 70
char = e;code = 101
char = 2;code = 50
char = O;code = 79
char = (;code = 40
char = B;code = 66
char = P;code = 80
char = H;code = 72
char = P;code = 80
char = A;code = 65
char = );code = 41
char = 2;code = 50
char = ];code = 93
char = 4;code = 52
char = +;code = 43
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = (;code = 40
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = g;code = 103
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = O;code = 79
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = v;code = 118
char = e;code = 101
char = r;code = 114
char = s;code = 115
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = r;code = 114
char = e;code = 101
char = );code = 41
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = u;code = 117
char = r;code = 114
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = .;code = 46
char = ;code = 32
char = E;code = 69
char = a;code = 97
char = c;code = 99
char = h;code = 104
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = o;code = 111
char = r;code = 114
char = d;code = 100
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = u;code = 117
char = r;code = 114
char = ;code = 32
char = N;code = 78
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = o;code = 111
char = m;code = 109
char = s;code = 115
char = ;code = 32
char = [;code = 91
char = F;code = 70
char = e;code = 101
char = -;code = 45
char = N;code = 78
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 2;code = 50
char = .;code = 46
char = 1;code = 49
char = 1;code = 49
char = 7;code = 55
char = ;code = 32
char = (;code = 40
char = 5;code = 53
char = );code = 41
char = -;code = 45
char = 2;code = 50
char = .;code = 46
char = 1;code = 49
char = 9;code = 57
char = 6;code = 54
char = ;code = 32
char = (;code = 40
char = 5;code = 53
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ];code = 93
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = O;code = 79
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = [;code = 91
char = F;code = 70
char = e;code = 101
char = -;code = 45
char = O;code = 79
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 2;code = 50
char = .;code = 46
char = 0;code = 48
char = 5;code = 53
char = 2;code = 50
char = ;code = 32
char = (;code = 40
char = 5;code = 53
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ];code = 93
char = ;code = 32
char = f;code = 102
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = B;code = 66
char = P;code = 80
char = H;code = 72
char = P;code = 80
char = A;code = 65
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ,;code = 44
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = g;code = 103
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = o;code = 111
char = x;code = 120
char = o;code = 111
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = [;code = 91
char = F;code = 70
char = e;code = 101
char = -;code = 45
char = O;code = 79
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 1;code = 49
char = .;code = 46
char = 7;code = 55
char = 8;code = 56
char = 9;code = 57
char = 6;code = 54
char = ;code = 32
char = (;code = 40
char = 9;code = 57
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ];code = 93
char = ,;code = 44
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = d;code = 100
char = i;code = 105
char = s;code = 115
char = t;code = 116
char = o;code = 111
char = r;code = 114
char = t;code = 116
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = o;code = 111
char = c;code = 99
char = t;code = 116
char = a;code = 97
char = h;code = 104
char = e;code = 101
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = .;code = 46
char = ;code = 32
char = T;code = 84
char = h;code = 104
char = e;code = 101
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = h;code = 104
char = y;code = 121
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = g;code = 103
char = e;code = 101
char = n;code = 110
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = s;code = 115
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = t;code = 116
char = w;code = 119
char = e;code = 101
char = e;code = 101
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = h;code = 104
char = y;code = 121
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = y;code = 121
char = ;code = 32
char = g;code = 103
char = r;code = 114
char = o;code = 111
char = u;code = 117
char = p;code = 112
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = O;code = 79
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = o;code = 111
char = m;code = 109
char = s;code = 115
char = ;code = 32
char = [;code = 91
char = O;code = 79
char = -;code = 45
char = H;code = 72
char = .;code = 46
char = .;code = 46
char = .;code = 46
char = O;code = 79
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 2;code = 50
char = .;code = 46
char = 6;code = 54
char = 5;code = 53
char = 4;code = 52
char = ;code = 32
char = (;code = 40
char = 7;code = 55
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ];code = 93
char = .;code = 46
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
result sql = The novel mu-oxo-diiron complex [Fe2O(BPHPA)2](ClO4)4 [BPHPA is (6-hydroxymethyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine, C19H20N4O], contains a binuclear centrosymmetric [Fe2O(BPHPA)2]4+ cation (the bridging O atom lies on an inversion centre) and four perchlorate anions. Each iron ion is coordinated by four N atoms [Fe-N = 2.117 (5)-2.196 (5) A] and one O atom [Fe-O = 2.052 (5) A] from a BPHPA ligand, and by one bridging oxo atom [Fe-O = 1.7896 (9) A], forming a distorted octahedron. There are hydrogen bonds between the hydroxy group and perchlorate O atoms [O-H...O = 2.654 (7) A].

Publication: Acta Crystallogr C 2005 Jan ;61(Pt 1)::m13-5.
Publication Date: 2005 Jan
Study Author(s): Gao, Yun-Ling;Peng, Xiao-Jun;Sun, Shi-Guo;Chen, Chang-Neng;
Institution: State Key Laboratory of Fine Chemicals, Dalian University of Technology, Dalian, Liaoning 116012, People's Republic of China.
Shortcut link to this study:
The novel mu-oxo-diiron complex [Fe2O(BPHPA)2](ClO4)4 [BPHPA is (6-hydroxymethyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine, C19H20N4O], contains a binuclear centrosymmetric [Fe2O(BPHPA)2]4+ cation (the bridging O atom lies on an inversion centre) and four perchlorate anions. Each iron ion is coordinated by four N atoms [Fe-N = 2.117 (5)-2.196 (5) A] and one O atom [Fe-O = 2.052 (5) A] from a BPHPA ligand, and by one bridging oxo atom [Fe-O = 1.7896 (9) A], forming a distorted octahedron. There are hydrogen bonds between the hydroxy group and perchlorate O atoms [O-H...O = 2.654 (7) A].
PMID: 15640566

Have comments? Post them here:

comments powered by Disqus

Get breaking news about nutritional cures, dangerous chemicals, superfoods . and more.

Subscribe to the FREE Natural News email newsletter. Your privacy is protected.