|
|
char = H;code = 72
char = o;code = 111
char = m;code = 109
char = o;code = 111
char = -;code = 45
char = /;code = 47
char = h;code = 104
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = o;code = 111
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = x;code = 120
char = e;code = 101
char = d;code = 100
char = -;code = 45
char = v;code = 118
char = a;code = 97
char = l;code = 108
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = o;code = 111
char = x;code = 120
char = o;code = 111
char = -;code = 45
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = /;code = 47
char = n;code = 110
char = i;code = 105
char = c;code = 99
char = k;code = 107
char = e;code = 101
char = l;code = 108
char = ;code = 32
char = c;code = 99
char = l;code = 108
char = u;code = 117
char = s;code = 115
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = s;code = 115
char = -;code = 45
char = M;code = 77
char = &;code = 38
char = #;code = 35
char = 2;code = 50
char = 4;code = 52
char = 6;code = 54
char = ;;code = 59
char = s;code = 115
char = s;code = 115
char = b;code = 98
char = a;code = 97
char = u;code = 117
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = u;code = 117
char = d;code = 100
char = i;code = 105
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = e;code = 101
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = -;code = 45
char = e;code = 101
char = x;code = 120
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = o;code = 111
char = c;code = 99
char = e;code = 101
char = s;code = 115
char = s;code = 115
char = e;code = 101
char = s;code = 115
char = .;code = 46
result sql = Homo-/heterotrinuclear mixed-valent oxo-centered iron/nickel clusters-Mössbauer studies on internal electron-exchange processes.
Homo-/heterotrinuclear mixed-valent oxo-centered iron/nickel clusters-Mössbauer studies on internal electron-exchange processes.char = I;code = 73
char = n;code = 110
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = e;code = 101
char = -;code = 45
char = p;code = 112
char = o;code = 111
char = t;code = 116
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = N;code = 78
char = -;code = 45
char = (;code = 40
char = 5;code = 53
char = -;code = 45
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = a;code = 97
char = z;code = 122
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = -;code = 45
char = 2;code = 50
char = -;code = 45
char = y;code = 121
char = l;code = 108
char = );code = 41
char = -;code = 45
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = a;code = 97
char = z;code = 122
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = -;code = 45
char = 2;code = 50
char = -;code = 45
char = c;code = 99
char = a;code = 97
char = r;code = 114
char = b;code = 98
char = o;code = 111
char = x;code = 120
char = a;code = 97
char = m;code = 109
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = H;code = 72
char = L;code = 76
char = 2;code = 50
char = ;code = 32
char = (;code = 40
char = 3;code = 51
char = );code = 41
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = ;code = 32
char = a;code = 97
char = c;code = 99
char = e;code = 101
char = t;code = 116
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = a;code = 97
char = i;code = 105
char = r;code = 114
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = h;code = 104
char = o;code = 111
char = m;code = 109
char = o;code = 111
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = h;code = 104
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = x;code = 120
char = e;code = 101
char = d;code = 100
char = -;code = 45
char = v;code = 118
char = a;code = 97
char = l;code = 108
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = o;code = 111
char = x;code = 120
char = o;code = 111
char = -;code = 45
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = c;code = 99
char = l;code = 108
char = u;code = 117
char = s;code = 115
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = [;code = 91
char = F;code = 70
char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = F;code = 70
char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
char = );code = 41
char = O;code = 79
char = (;code = 40
char = L;code = 76
char = 2;code = 50
char = );code = 41
char = 3;code = 51
char = (;code = 40
char = O;code = 79
char = A;code = 65
char = c;code = 99
char = );code = 41
char = 3;code = 51
char = ];code = 93
char = ;code = 32
char = (;code = 40
char = 4;code = 52
char = );code = 41
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = e;code = 101
char = d;code = 100
char = .;code = 46
char = ;code = 32
char = E;code = 69
char = x;code = 120
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = 4;code = 52
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = n;code = 110
char = i;code = 105
char = c;code = 99
char = k;code = 107
char = e;code = 101
char = l;code = 108
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = ;code = 32
char = a;code = 97
char = f;code = 102
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = d;code = 100
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = h;code = 104
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = c;code = 99
char = l;code = 108
char = u;code = 117
char = s;code = 115
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = [;code = 91
char = N;code = 78
char = i;code = 105
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = F;code = 70
char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
char = );code = 41
char = O;code = 79
char = (;code = 40
char = L;code = 76
char = 2;code = 50
char = );code = 41
char = 3;code = 51
char = (;code = 40
char = O;code = 79
char = A;code = 65
char = c;code = 99
char = );code = 41
char = 3;code = 51
char = ];code = 93
char = ;code = 32
char = (;code = 40
char = 6;code = 54
char = );code = 41
char = .;code = 46
char = ;code = 32
char = T;code = 84
char = o;code = 111
char = ;code = 32
char = o;code = 111
char = b;code = 98
char = t;code = 116
char = a;code = 97
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = c;code = 99
char = r;code = 114
char = y;code = 121
char = s;code = 115
char = t;code = 116
char = a;code = 97
char = l;code = 108
char = s;code = 115
char = ;code = 32
char = s;code = 115
char = u;code = 117
char = i;code = 105
char = t;code = 116
char = a;code = 97
char = b;code = 98
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = ;code = 32
char = X;code = 88
char = -;code = 45
char = r;code = 114
char = a;code = 97
char = y;code = 121
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = u;code = 117
char = c;code = 99
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = y;code = 121
char = s;code = 115
char = e;code = 101
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = 4;code = 52
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = 6;code = 54
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = O;code = 79
char = A;code = 65
char = c;code = 99
char = -;code = 45
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = -;code = 45
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = s;code = 115
char = ;code = 32
char = w;code = 119
char = e;code = 101
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = O;code = 79
char = B;code = 66
char = z;code = 122
char = -;code = 45
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = s;code = 115
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = g;code = 103
char = i;code = 105
char = v;code = 118
char = e;code = 101
char = ;code = 32
char = [;code = 91
char = F;code = 70
char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = F;code = 70
char = e;code = 101
char = 2;code = 50
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
char = );code = 41
char = O;code = 79
char = (;code = 40
char = L;code = 76
char = 2;code = 50
char = );code = 41
char = 3;code = 51
char = (;code = 40
char = O;code = 79
char = B;code = 66
char = z;code = 122
char = );code = 41
char = 3;code = 51
char = ];code = 93
char = ;code = 32
char = (;code = 40
char = 5;code = 53
char = );code = 41
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = [;code = 91
char = N;code = 78
char = i;code = 105
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = F;code = 70
char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
char = );code = 41
char = O;code = 79
char = (;code = 40
char = L;code = 76
char = 2;code = 50
char = );code = 41
char = 3;code = 51
char = (;code = 40
char = O;code = 79
char = B;code = 66
char = z;code = 122
char = );code = 41
char = 3;code = 51
char = ];code = 93
char = ;code = 32
char = (;code = 40
char = 7;code = 55
char = );code = 41
char = .;code = 46
char = ;code = 32
char = T;code = 84
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = m;code = 109
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = x;code = 120
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = 5;code = 53
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = 7;code = 55
char = ;code = 32
char = a;code = 97
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = i;code = 105
char = s;code = 115
char = o;code = 111
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = u;code = 117
char = c;code = 99
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = a;code = 97
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = u;code = 117
char = p;code = 112
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = r;code = 114
char = e;code = 101
char = e;code = 101
char = ;code = 32
char = d;code = 100
char = i;code = 105
char = t;code = 116
char = o;code = 111
char = p;code = 112
char = i;code = 105
char = c;code = 99
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = s;code = 115
char = ;code = 32
char = (;code = 40
char = L;code = 76
char = 2;code = 50
char = );code = 41
char = -;code = 45
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = r;code = 114
char = e;code = 101
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = g;code = 103
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = n;code = 110
char = z;code = 122
char = o;code = 111
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = -;code = 45
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = w;code = 119
char = h;code = 104
char = i;code = 105
char = c;code = 99
char = h;code = 104
char = ;code = 32
char = f;code = 102
char = i;code = 105
char = x;code = 120
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = r;code = 114
char = e;code = 101
char = e;code = 101
char = ;code = 32
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = r;code = 114
char = n;code = 110
char = e;code = 101
char = r;code = 114
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = ;code = 32
char = m;code = 109
char = u;code = 117
char = 3;code = 51
char = -;code = 45
char = O;code = 79
char = 2;code = 50
char = -;code = 45
char = ;code = 32
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = .;code = 46
char = ;code = 32
char = T;code = 84
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = x;code = 120
char = e;code = 101
char = d;code = 100
char = -;code = 45
char = v;code = 118
char = a;code = 97
char = l;code = 108
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = r;code = 114
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = 4;code = 52
char = -;code = 45
char = 7;code = 55
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = i;code = 105
char = r;code = 114
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = m;code = 109
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = e;code = 101
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = -;code = 45
char = e;code = 101
char = x;code = 120
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = o;code = 111
char = c;code = 99
char = e;code = 101
char = s;code = 115
char = s;code = 115
char = e;code = 101
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = i;code = 105
char = r;code = 114
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = d;code = 100
char = o;code = 111
char = x;code = 120
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = o;code = 111
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = t;code = 116
char = i;code = 105
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = w;code = 119
char = e;code = 101
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = u;code = 117
char = d;code = 100
char = i;code = 105
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = v;code = 118
char = a;code = 97
char = r;code = 114
char = i;code = 105
char = a;code = 97
char = b;code = 98
char = l;code = 108
char = e;code = 101
char = -;code = 45
char = t;code = 116
char = e;code = 101
char = m;code = 109
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = M;code = 77
char = &;code = 38
char = #;code = 35
char = 2;code = 50
char = 4;code = 52
char = 6;code = 54
char = ;;code = 59
char = s;code = 115
char = s;code = 115
char = b;code = 98
char = a;code = 97
char = u;code = 117
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = s;code = 115
char = p;code = 112
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = s;code = 115
char = c;code = 99
char = o;code = 111
char = p;code = 112
char = y;code = 121
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = c;code = 99
char = y;code = 121
char = c;code = 99
char = l;code = 108
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = v;code = 118
char = o;code = 111
char = l;code = 108
char = t;code = 116
char = a;code = 97
char = m;code = 109
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = r;code = 114
char = y;code = 121
char = .;code = 46
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = /;code = 47
char = >;code = 62
result sql = In a one-pot reaction of N-(5-methylthiazole-2-yl)-thiazole-2-carboxamide HL2 (3) with iron(II) acetate in air, the homotrinuclear heteroleptic mixed-valent oxo-centered iron cluster [Fe(II)Fe(III)O(L2)3(OAc)3] (4) was formed. Exchange of iron(II) in 4 by nickel(II) afforded the heteronuclear cluster [Ni(II)Fe(III)O(L2)3(OAc)3] (6). To obtain crystals suitable for X-ray structure analyses, in 4 and 6, the OAc- co-ligands were exchanged by OBz- ligands to give [Fe(II)Fe2(III)O(L2)3(OBz)3] (5) and [Ni(II)Fe(III)O(L2)3(OBz)3] (7). The complexes 5 and 7 are isostructural and made up of three ditopic, tridentate ligands (L2)- and three bridging benzoate co-ligands, which fix the three metal ions in the corners of a triangle with an mu3-O2- ion in the center. The mixed-valent character of 4-7, their intramolecular electron-exchange processes, and their redox properties were studied by variable-temperature Mössbauer spectroscopy and cyclic voltammetry.
char = o;code = 111
char = m;code = 109
char = o;code = 111
char = -;code = 45
char = /;code = 47
char = h;code = 104
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = o;code = 111
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = x;code = 120
char = e;code = 101
char = d;code = 100
char = -;code = 45
char = v;code = 118
char = a;code = 97
char = l;code = 108
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = o;code = 111
char = x;code = 120
char = o;code = 111
char = -;code = 45
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = /;code = 47
char = n;code = 110
char = i;code = 105
char = c;code = 99
char = k;code = 107
char = e;code = 101
char = l;code = 108
char = ;code = 32
char = c;code = 99
char = l;code = 108
char = u;code = 117
char = s;code = 115
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = s;code = 115
char = -;code = 45
char = M;code = 77
char = &;code = 38
char = #;code = 35
char = 2;code = 50
char = 4;code = 52
char = 6;code = 54
char = ;;code = 59
char = s;code = 115
char = s;code = 115
char = b;code = 98
char = a;code = 97
char = u;code = 117
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = u;code = 117
char = d;code = 100
char = i;code = 105
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = e;code = 101
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = -;code = 45
char = e;code = 101
char = x;code = 120
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = o;code = 111
char = c;code = 99
char = e;code = 101
char = s;code = 115
char = s;code = 115
char = e;code = 101
char = s;code = 115
char = .;code = 46
result sql = Homo-/heterotrinuclear mixed-valent oxo-centered iron/nickel clusters-Mössbauer studies on internal electron-exchange processes.
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char = ;code = 32
char = a;code = 97
char = ;code = 32
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char = p;code = 112
char = o;code = 111
char = t;code = 116
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = N;code = 78
char = -;code = 45
char = (;code = 40
char = 5;code = 53
char = -;code = 45
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = h;code = 104
char = y;code = 121
char = l;code = 108
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = a;code = 97
char = z;code = 122
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = -;code = 45
char = 2;code = 50
char = -;code = 45
char = y;code = 121
char = l;code = 108
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char = -;code = 45
char = t;code = 116
char = h;code = 104
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char = z;code = 122
char = o;code = 111
char = l;code = 108
char = e;code = 101
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char = -;code = 45
char = c;code = 99
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char = r;code = 114
char = b;code = 98
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char = i;code = 105
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char = a;code = 97
char = t;code = 116
char = e;code = 101
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char = i;code = 105
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char = ;code = 32
char = a;code = 97
char = i;code = 105
char = r;code = 114
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = h;code = 104
char = o;code = 111
char = m;code = 109
char = o;code = 111
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
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char = h;code = 104
char = e;code = 101
char = t;code = 116
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char = o;code = 111
char = l;code = 108
char = e;code = 101
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = m;code = 109
char = i;code = 105
char = x;code = 120
char = e;code = 101
char = d;code = 100
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char = v;code = 118
char = a;code = 97
char = l;code = 108
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = o;code = 111
char = x;code = 120
char = o;code = 111
char = -;code = 45
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = c;code = 99
char = l;code = 108
char = u;code = 117
char = s;code = 115
char = t;code = 116
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char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
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char = F;code = 70
char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
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char = O;code = 79
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char = L;code = 76
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char = 3;code = 51
char = (;code = 40
char = O;code = 79
char = A;code = 65
char = c;code = 99
char = );code = 41
char = 3;code = 51
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char = ;code = 32
char = (;code = 40
char = 4;code = 52
char = );code = 41
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = e;code = 101
char = d;code = 100
char = .;code = 46
char = ;code = 32
char = E;code = 69
char = x;code = 120
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = i;code = 105
char = r;code = 114
char = o;code = 111
char = n;code = 110
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = 4;code = 52
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = n;code = 110
char = i;code = 105
char = c;code = 99
char = k;code = 107
char = e;code = 101
char = l;code = 108
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char = I;code = 73
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char = ;code = 32
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char = f;code = 102
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char = o;code = 111
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char = d;code = 100
char = e;code = 101
char = d;code = 100
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char = h;code = 104
char = e;code = 101
char = ;code = 32
char = h;code = 104
char = e;code = 101
char = t;code = 116
char = e;code = 101
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char = o;code = 111
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = c;code = 99
char = l;code = 108
char = u;code = 117
char = s;code = 115
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = [;code = 91
char = N;code = 78
char = i;code = 105
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = F;code = 70
char = e;code = 101
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char = I;code = 73
char = I;code = 73
char = I;code = 73
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char = (;code = 40
char = O;code = 79
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char = c;code = 99
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char = 3;code = 51
char = ];code = 93
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char = (;code = 40
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char = );code = 41
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char = ;code = 32
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char = ;code = 32
char = o;code = 111
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char = t;code = 116
char = a;code = 97
char = i;code = 105
char = n;code = 110
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char = r;code = 114
char = y;code = 121
char = s;code = 115
char = t;code = 116
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char = l;code = 108
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char = s;code = 115
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char = i;code = 105
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char = e;code = 101
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char = f;code = 102
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char = ;code = 32
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char = s;code = 115
char = t;code = 116
char = r;code = 114
char = u;code = 117
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char = t;code = 116
char = u;code = 117
char = r;code = 114
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char = a;code = 97
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char = ;code = 32
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char = e;code = 101
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char = h;code = 104
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char = n;code = 110
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char = e;code = 101
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char = b;code = 98
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char = e;code = 101
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char = 3;code = 51
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char = z;code = 122
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char = 3;code = 51
char = ];code = 93
char = ;code = 32
char = (;code = 40
char = 5;code = 53
char = );code = 41
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = [;code = 91
char = N;code = 78
char = i;code = 105
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = );code = 41
char = F;code = 70
char = e;code = 101
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
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char = O;code = 79
char = (;code = 40
char = L;code = 76
char = 2;code = 50
char = );code = 41
char = 3;code = 51
char = (;code = 40
char = O;code = 79
char = B;code = 66
char = z;code = 122
char = );code = 41
char = 3;code = 51
char = ];code = 93
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char = (;code = 40
char = 7;code = 55
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char = .;code = 46
char = ;code = 32
char = T;code = 84
char = h;code = 104
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char = c;code = 99
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char = d;code = 100
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char = 7;code = 55
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char = i;code = 105
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char = o;code = 111
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char = u;code = 117
char = c;code = 99
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result sql = In a one-pot reaction of N-(5-methylthiazole-2-yl)-thiazole-2-carboxamide HL2 (3) with iron(II) acetate in air, the homotrinuclear heteroleptic mixed-valent oxo-centered iron cluster [Fe(II)Fe(III)O(L2)3(OAc)3] (4) was formed. Exchange of iron(II) in 4 by nickel(II) afforded the heteronuclear cluster [Ni(II)Fe(III)O(L2)3(OAc)3] (6). To obtain crystals suitable for X-ray structure analyses, in 4 and 6, the OAc- co-ligands were exchanged by OBz- ligands to give [Fe(II)Fe2(III)O(L2)3(OBz)3] (5) and [Ni(II)Fe(III)O(L2)3(OBz)3] (7). The complexes 5 and 7 are isostructural and made up of three ditopic, tridentate ligands (L2)- and three bridging benzoate co-ligands, which fix the three metal ions in the corners of a triangle with an mu3-O2- ion in the center. The mixed-valent character of 4-7, their intramolecular electron-exchange processes, and their redox properties were studied by variable-temperature Mössbauer spectroscopy and cyclic voltammetry.
Publication: Chemistry 2005 Oct 7 ;11(20)::5843-8.
Publication Date: 2005 Oct 7
Study Author(s): Saalfrank, Rolf W;Scheurer, Andreas;Reimann, Uwe;Hampel, Frank;Trieflinger, Christian;Büschel, Michael;Daub, Jörg;Trautwein, Alfred X;Schünemann, Volker;Coropceanu, Veaceslav;
Institution: Institut für Organische Chemie der Universität Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany. [email protected]
Shortcut link to this study:
Publication Date: 2005 Oct 7
Study Author(s): Saalfrank, Rolf W;Scheurer, Andreas;Reimann, Uwe;Hampel, Frank;Trieflinger, Christian;Büschel, Michael;Daub, Jörg;Trautwein, Alfred X;Schünemann, Volker;Coropceanu, Veaceslav;
Institution: Institut für Organische Chemie der Universität Erlangen-Nürnberg, Henkestrasse 42, 91054 Erlangen, Germany. [email protected]
Shortcut link to this study:
In a one-pot reaction of N-(5-methylthiazole-2-yl)-thiazole-2-carboxamide HL2 (3) with iron(II) acetate in air, the homotrinuclear heteroleptic mixed-valent oxo-centered iron cluster [Fe(II)Fe(III)O(L2)3(OAc)3] (4) was formed. Exchange of iron(II) in 4 by nickel(II) afforded the heteronuclear cluster [Ni(II)Fe(III)O(L2)3(OAc)3] (6). To obtain crystals suitable for X-ray structure analyses, in 4 and 6, the OAc- co-ligands were exchanged by OBz- ligands to give [Fe(II)Fe2(III)O(L2)3(OBz)3] (5) and [Ni(II)Fe(III)O(L2)3(OBz)3] (7). The complexes 5 and 7 are isostructural and made up of three ditopic, tridentate ligands (L2)- and three bridging benzoate co-ligands, which fix the three metal ions in the corners of a triangle with an mu3-O2- ion in the center. The mixed-valent character of 4-7, their intramolecular electron-exchange processes, and their redox properties were studied by variable-temperature Mössbauer spectroscopy and cyclic voltammetry.
PMID: 16041808
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