|
|
char = S;code = 83
char = e;code = 101
char = l;code = 108
char = f;code = 102
char = -;code = 45
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char = s;code = 115
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char = m;code = 109
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char = c;code = 99
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char = m;code = 109
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char = I;code = 73
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char = I;code = 73
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char = c;code = 99
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char = l;code = 108
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char = i;code = 105
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char = b;code = 98
char = l;code = 108
char = o;code = 111
char = c;code = 99
char = k;code = 107
char = .;code = 46
result sql = Self-assembly supramolecular architectures of chromium(III) complexes using croconate as building block.
Self-assembly supramolecular architectures of chromium(III) complexes using croconate as building block.char = T;code = 84
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char = t;code = 116
char = r;code = 114
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char = t;code = 116
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char = C;code = 67
char = r;code = 114
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char = I;code = 73
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char = r;code = 114
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char = r;code = 114
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char = m;code = 109
char = u;code = 117
char = -;code = 45
char = C;code = 67
char = 5;code = 53
char = O;code = 79
char = 5;code = 53
char = );code = 41
char = (;code = 40
char = m;code = 109
char = i;code = 105
char = c;code = 99
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char = o;code = 111
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char = O;code = 79
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char = (;code = 40
char = O;code = 79
char = H;code = 72
char = 2;code = 50
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char = ];code = 93
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char = g;code = 103
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char = u;code = 117
char = p;code = 112
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char = C;code = 67
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char = H;code = 72
char = ;code = 32
char = h;code = 104
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char = d;code = 100
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char = g;code = 103
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char = u;code = 117
char = p;code = 112
char = ;code = 32
char = a;code = 97
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char = o;code = 111
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char = l;code = 108
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char = g;code = 103
char = a;code = 97
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char = d;code = 100
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char = a;code = 97
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char = s;code = 115
char = ;code = 32
char = w;code = 119
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char = t;code = 116
char = h;code = 104
char = ;code = 32
char = v;code = 118
char = i;code = 105
char = c;code = 99
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = C;code = 67
char = [;code = 91
char = d;code = 100
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char = b;code = 98
char = l;code = 108
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char = ;code = 32
char = b;code = 98
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char = d;code = 100
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char = a;code = 97
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char = p;code = 112
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char = 2;code = 50
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result sql = The synthesis, X-ray structure and magnetic properties of polynuclear Cr(III) complexes with the croconate ligand (C5O5(2-)) are reported: [Cr(mu-C5O5)(micro-OH)(OH2)2]2 x 6H2O (, orthorombic, space group Cmca, a = 6.741(7) A, b = 18.841(9) A, c = 16.886(9) A, V = 2145(3) A3) shows a dinuclear structure with two mu-OH hydroxo group and two ligand molecules that are bridging two metal centers with vicinal C[double bond, length as m-dash]O groups (micro-kappa2O,O coordination mode), the octahedral geometry of the Cr atoms being completed by the coordination of the O atom of the water molecule and [Cr(micro-C5O5)(micro-OH)(OH2)2]2[K5(C5O5)2.5] x 7H2O (, monoclinic, space group Cc, a = 15.216(9) A, b = 14.895(8) A, c = 18.503(9) A, beta = 96.77(5) degrees and V = 4164(4) A3), a polymer showing various coordination geometries of the K(I) cations. Magnetic susceptibility measurements, performed on , in the 5-400 K temperature range, show antiferromagnetic interactions with J1/k = -50.2 +/- 0.1 K and J2/k approximately -3 K with J1 and J2 the intradimer and interdimer interaction constants, respectively. DFT calculations, performed to gain insight into the coupling between the two metal centers and characterize their spin and charge distribution in the hydroxo-bridged dinuclear entities, are in good agreement with experimental findings.
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result sql = Self-assembly supramolecular architectures of chromium(III) complexes using croconate as building block.
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char = 1;code = 49
char = (;code = 40
char = 9;code = 57
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ,;code = 44
char = ;code = 32
char = c;code = 99
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 1;code = 49
char = 6;code = 54
char = .;code = 46
char = 8;code = 56
char = 8;code = 56
char = 6;code = 54
char = (;code = 40
char = 9;code = 57
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ,;code = 44
char = ;code = 32
char = V;code = 86
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 2;code = 50
char = 1;code = 49
char = 4;code = 52
char = 5;code = 53
char = (;code = 40
char = 3;code = 51
char = );code = 41
char = ;code = 32
char = A;code = 65
char = 3;code = 51
char = );code = 41
char = ;code = 32
char = s;code = 115
char = h;code = 104
char = o;code = 111
char = w;code = 119
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = d;code = 100
char = i;code = 105
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = r;code = 114
char = u;code = 117
char = c;code = 99
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = t;code = 116
char = w;code = 119
char = o;code = 111
char = ;code = 32
char = m;code = 109
char = u;code = 117
char = -;code = 45
char = O;code = 79
char = H;code = 72
char = ;code = 32
char = h;code = 104
char = y;code = 121
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = o;code = 111
char = ;code = 32
char = g;code = 103
char = r;code = 114
char = o;code = 111
char = u;code = 117
char = p;code = 112
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = t;code = 116
char = w;code = 119
char = o;code = 111
char = ;code = 32
char = l;code = 108
char = i;code = 105
char = g;code = 103
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = t;code = 116
char = ;code = 32
char = a;code = 97
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = d;code = 100
char = g;code = 103
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = t;code = 116
char = w;code = 119
char = o;code = 111
char = ;code = 32
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = s;code = 115
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = v;code = 118
char = i;code = 105
char = c;code = 99
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = C;code = 67
char = [;code = 91
char = d;code = 100
char = o;code = 111
char = u;code = 117
char = b;code = 98
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = ,;code = 44
char = ;code = 32
char = l;code = 108
char = e;code = 101
char = n;code = 110
char = g;code = 103
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = m;code = 109
char = -;code = 45
char = d;code = 100
char = a;code = 97
char = s;code = 115
char = h;code = 104
char = ];code = 93
char = O;code = 79
char = ;code = 32
char = g;code = 103
char = r;code = 114
char = o;code = 111
char = u;code = 117
char = p;code = 112
char = s;code = 115
char = ;code = 32
char = (;code = 40
char = m;code = 109
char = i;code = 105
char = c;code = 99
char = r;code = 114
char = o;code = 111
char = -;code = 45
char = k;code = 107
char = a;code = 97
char = p;code = 112
char = p;code = 112
char = a;code = 97
char = 2;code = 50
char = O;code = 79
char = ,;code = 44
char = O;code = 79
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = o;code = 111
char = r;code = 114
char = d;code = 100
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = d;code = 100
char = e;code = 101
char = );code = 41
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = c;code = 99
char = t;code = 116
char = a;code = 97
char = h;code = 104
char = e;code = 101
char = d;code = 100
char = r;code = 114
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = g;code = 103
char = e;code = 101
char = o;code = 111
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = r;code = 114
char = y;code = 121
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = C;code = 67
char = r;code = 114
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = o;code = 111
char = m;code = 109
char = s;code = 115
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = m;code = 109
char = p;code = 112
char = l;code = 108
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = b;code = 98
char = y;code = 121
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = o;code = 111
char = r;code = 114
char = d;code = 100
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = O;code = 79
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = [;code = 91
char = C;code = 67
char = r;code = 114
char = (;code = 40
char = m;code = 109
char = i;code = 105
char = c;code = 99
char = r;code = 114
char = o;code = 111
char = -;code = 45
char = C;code = 67
char = 5;code = 53
char = O;code = 79
char = 5;code = 53
char = );code = 41
char = (;code = 40
char = m;code = 109
char = i;code = 105
char = c;code = 99
char = r;code = 114
char = o;code = 111
char = -;code = 45
char = O;code = 79
char = H;code = 72
char = );code = 41
char = (;code = 40
char = O;code = 79
char = H;code = 72
char = 2;code = 50
char = );code = 41
char = 2;code = 50
char = ];code = 93
char = 2;code = 50
char = [;code = 91
char = K;code = 75
char = 5;code = 53
char = (;code = 40
char = C;code = 67
char = 5;code = 53
char = O;code = 79
char = 5;code = 53
char = );code = 41
char = 2;code = 50
char = .;code = 46
char = 5;code = 53
char = ];code = 93
char = ;code = 32
char = x;code = 120
char = ;code = 32
char = 7;code = 55
char = H;code = 72
char = 2;code = 50
char = O;code = 79
char = ;code = 32
char = (;code = 40
char = ,;code = 44
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = o;code = 111
char = c;code = 99
char = l;code = 108
char = i;code = 105
char = n;code = 110
char = i;code = 105
char = c;code = 99
char = ,;code = 44
char = ;code = 32
char = s;code = 115
char = p;code = 112
char = a;code = 97
char = c;code = 99
char = e;code = 101
char = ;code = 32
char = g;code = 103
char = r;code = 114
char = o;code = 111
char = u;code = 117
char = p;code = 112
char = ;code = 32
char = C;code = 67
char = c;code = 99
char = ,;code = 44
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 1;code = 49
char = 5;code = 53
char = .;code = 46
char = 2;code = 50
char = 1;code = 49
char = 6;code = 54
char = (;code = 40
char = 9;code = 57
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ,;code = 44
char = ;code = 32
char = b;code = 98
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 1;code = 49
char = 4;code = 52
char = .;code = 46
char = 8;code = 56
char = 9;code = 57
char = 5;code = 53
char = (;code = 40
char = 8;code = 56
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ,;code = 44
char = ;code = 32
char = c;code = 99
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 1;code = 49
char = 8;code = 56
char = .;code = 46
char = 5;code = 53
char = 0;code = 48
char = 3;code = 51
char = (;code = 40
char = 9;code = 57
char = );code = 41
char = ;code = 32
char = A;code = 65
char = ,;code = 44
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = t;code = 116
char = a;code = 97
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 9;code = 57
char = 6;code = 54
char = .;code = 46
char = 7;code = 55
char = 7;code = 55
char = (;code = 40
char = 5;code = 53
char = );code = 41
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = g;code = 103
char = r;code = 114
char = e;code = 101
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = V;code = 86
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 4;code = 52
char = 1;code = 49
char = 6;code = 54
char = 4;code = 52
char = (;code = 40
char = 4;code = 52
char = );code = 41
char = ;code = 32
char = A;code = 65
char = 3;code = 51
char = );code = 41
char = ,;code = 44
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = p;code = 112
char = o;code = 111
char = l;code = 108
char = y;code = 121
char = m;code = 109
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = s;code = 115
char = h;code = 104
char = o;code = 111
char = w;code = 119
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = v;code = 118
char = a;code = 97
char = r;code = 114
char = i;code = 105
char = o;code = 111
char = u;code = 117
char = s;code = 115
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = o;code = 111
char = r;code = 114
char = d;code = 100
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = g;code = 103
char = e;code = 101
char = o;code = 111
char = m;code = 109
char = e;code = 101
char = t;code = 116
char = r;code = 114
char = i;code = 105
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = K;code = 75
char = (;code = 40
char = I;code = 73
char = );code = 41
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = .;code = 46
char = ;code = 32
char = M;code = 77
char = a;code = 97
char = g;code = 103
char = n;code = 110
char = e;code = 101
char = t;code = 116
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = s;code = 115
char = u;code = 117
char = s;code = 115
char = c;code = 99
char = e;code = 101
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = b;code = 98
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = t;code = 116
char = y;code = 121
char = ;code = 32
char = m;code = 109
char = e;code = 101
char = a;code = 97
char = s;code = 115
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = m;code = 109
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = ,;code = 44
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = 5;code = 53
char = -;code = 45
char = 4;code = 52
char = 0;code = 48
char = 0;code = 48
char = ;code = 32
char = K;code = 75
char = ;code = 32
char = t;code = 116
char = e;code = 101
char = m;code = 109
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = r;code = 114
char = a;code = 97
char = n;code = 110
char = g;code = 103
char = e;code = 101
char = ,;code = 44
char = ;code = 32
char = s;code = 115
char = h;code = 104
char = o;code = 111
char = w;code = 119
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = t;code = 116
char = i;code = 105
char = f;code = 102
char = e;code = 101
char = r;code = 114
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = a;code = 97
char = g;code = 103
char = n;code = 110
char = e;code = 101
char = t;code = 116
char = i;code = 105
char = c;code = 99
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char = i;code = 105
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = J;code = 74
char = 1;code = 49
char = /;code = 47
char = k;code = 107
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = -;code = 45
char = 5;code = 53
char = 0;code = 48
char = .;code = 46
char = 2;code = 50
char = ;code = 32
char = +;code = 43
char = /;code = 47
char = -;code = 45
char = ;code = 32
char = 0;code = 48
char = .;code = 46
char = 1;code = 49
char = ;code = 32
char = K;code = 75
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = J;code = 74
char = 2;code = 50
char = /;code = 47
char = k;code = 107
char = ;code = 32
char = a;code = 97
char = p;code = 112
char = p;code = 112
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = m;code = 109
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = l;code = 108
char = y;code = 121
char = ;code = 32
char = -;code = 45
char = 3;code = 51
char = ;code = 32
char = K;code = 75
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = J;code = 74
char = 1;code = 49
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = J;code = 74
char = 2;code = 50
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = r;code = 114
char = a;code = 97
char = d;code = 100
char = i;code = 105
char = m;code = 109
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = d;code = 100
char = i;code = 105
char = m;code = 109
char = e;code = 101
char = r;code = 114
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = t;code = 116
char = a;code = 97
char = n;code = 110
char = t;code = 116
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = p;code = 112
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = v;code = 118
char = e;code = 101
char = l;code = 108
char = y;code = 121
char = .;code = 46
char = ;code = 32
char = D;code = 68
char = F;code = 70
char = T;code = 84
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = l;code = 108
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = g;code = 103
char = a;code = 97
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = s;code = 115
char = i;code = 105
char = g;code = 103
char = h;code = 104
char = t;code = 116
char = ;code = 32
char = i;code = 105
char = n;code = 110
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result sql = The synthesis, X-ray structure and magnetic properties of polynuclear Cr(III) complexes with the croconate ligand (C5O5(2-)) are reported: [Cr(mu-C5O5)(micro-OH)(OH2)2]2 x 6H2O (, orthorombic, space group Cmca, a = 6.741(7) A, b = 18.841(9) A, c = 16.886(9) A, V = 2145(3) A3) shows a dinuclear structure with two mu-OH hydroxo group and two ligand molecules that are bridging two metal centers with vicinal C[double bond, length as m-dash]O groups (micro-kappa2O,O coordination mode), the octahedral geometry of the Cr atoms being completed by the coordination of the O atom of the water molecule and [Cr(micro-C5O5)(micro-OH)(OH2)2]2[K5(C5O5)2.5] x 7H2O (, monoclinic, space group Cc, a = 15.216(9) A, b = 14.895(8) A, c = 18.503(9) A, beta = 96.77(5) degrees and V = 4164(4) A3), a polymer showing various coordination geometries of the K(I) cations. Magnetic susceptibility measurements, performed on , in the 5-400 K temperature range, show antiferromagnetic interactions with J1/k = -50.2 +/- 0.1 K and J2/k approximately -3 K with J1 and J2 the intradimer and interdimer interaction constants, respectively. DFT calculations, performed to gain insight into the coupling between the two metal centers and characterize their spin and charge distribution in the hydroxo-bridged dinuclear entities, are in good agreement with experimental findings.
Publication: Dalton Trans 2009 Jan 21 ;(3)::557-63. :doi: 10.1039/b810216n.
Publication Date: 2009 Jan 21
Study Author(s): Salidu, Marco;Artizzu, Flavia;Deplano, Paola;Mercuri, Maria Laura;Pilia, Luca;Serpe, Angela;Marchiò, Luciano;Concas, Giorgio;Congiu, Francesco;
Institution: Dipartimento di Chimica Inorganica ed Analitica, Università di Cagliari, Cittadella di Monserrato, I-09042 Monserrato, Cagliari, Italy.
Shortcut link to this study:
Publication Date: 2009 Jan 21
Study Author(s): Salidu, Marco;Artizzu, Flavia;Deplano, Paola;Mercuri, Maria Laura;Pilia, Luca;Serpe, Angela;Marchiò, Luciano;Concas, Giorgio;Congiu, Francesco;
Institution: Dipartimento di Chimica Inorganica ed Analitica, Università di Cagliari, Cittadella di Monserrato, I-09042 Monserrato, Cagliari, Italy.
Shortcut link to this study:
The synthesis, X-ray structure and magnetic properties of polynuclear Cr(III) complexes with the croconate ligand (C5O5(2-)) are reported: [Cr(mu-C5O5)(micro-OH)(OH2)2]2 x 6H2O (, orthorombic, space group Cmca, a = 6.741(7) A, b = 18.841(9) A, c = 16.886(9) A, V = 2145(3) A3) shows a dinuclear structure with two mu-OH hydroxo group and two ligand molecules that are bridging two metal centers with vicinal C[double bond, length as m-dash]O groups (micro-kappa2O,O coordination mode), the octahedral geometry of the Cr atoms being completed by the coordination of the O atom of the water molecule and [Cr(micro-C5O5)(micro-OH)(OH2)2]2[K5(C5O5)2.5] x 7H2O (, monoclinic, space group Cc, a = 15.216(9) A, b = 14.895(8) A, c = 18.503(9) A, beta = 96.77(5) degrees and V = 4164(4) A3), a polymer showing various coordination geometries of the K(I) cations. Magnetic susceptibility measurements, performed on , in the 5-400 K temperature range, show antiferromagnetic interactions with J1/k = -50.2 +/- 0.1 K and J2/k approximately -3 K with J1 and J2 the intradimer and interdimer interaction constants, respectively. DFT calculations, performed to gain insight into the coupling between the two metal centers and characterize their spin and charge distribution in the hydroxo-bridged dinuclear entities, are in good agreement with experimental findings.
PMID: 19122914
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