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result sql = Chemometric study and optimization of extraction parameters in single-drop microextraction for the determination of multiclass pesticide residues in grapes and apples by gas chromatography mass spectrometry.
Chemometric study and optimization of extraction parameters in single-drop microextraction for the determination of multiclass pesticide residues in grapes and apples by gas chromatography mass spectrometry.
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char = ;code = 32
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char = a;code = 97
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char = d;code = 100
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char = d;code = 100
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char = i;code = 105
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result sql = A simple and rapid single-drop microextraction method coupled with gas chromatography and mass spectrometry (SDME-GC/MS) for the determination of 20 pesticides with different physicochemical properties in grapes and apples was optimized by the use of a multivariate strategy. Emphasis on the optimization study was given to the role of ionic strength, sugar concentration and pH of the donor sample solution prepared from the fruit samples. Since all three variables were found to affect negatively SDME (a lower extraction efficiency was observed as the values of variables were increased for most of the pesticides studied), donor sample solution was optimized using a central composite design to evaluate the optimum pH value and the optimum dilution of the sample extract. With some exceptions (chlorpyrifos ethyl, alpha-endosulfan, beta-endosulfan, pyriproxyfen, lambda-cyhalothrin and bifenthrin), the optimum method included the dilution of the analytical sample by 12.5-fold with a buffered acetone/water solution at pH=4 and exhibited good analytical characteristics for the majority of target analytes (pyrimethanil, pirimicarb, metribuzin, vinclozolin, fosthiazate, procymidone, fludioxonil, kresoxim methyl, endosulfan sulfate, fenhexamid, iprodione, phosalone, indoxacarb and azoxystrobin) by providing high enrichment factors (14-328), low limits of detection (0.0003-0.007 microg/g), and good precision (relative standard deviations below 15%).

Publication: J Chromatogr A 2009 Nov 6 ;1216(45)::7630-8. :doi: 10.1016/j.chroma.2009.08.092.
Publication Date: 2009 Nov 6
Study Author(s): Amvrazi, Elpiniki G;Tsiropoulos, Nikolaos G;
Institution: Department of Agriculture, Crop Production and Rural Environment, University of Thessaly, Fytokou Str., 38446 Nea Ionia - Volos, Greece.
Shortcut link to this study:
A simple and rapid single-drop microextraction method coupled with gas chromatography and mass spectrometry (SDME-GC/MS) for the determination of 20 pesticides with different physicochemical properties in grapes and apples was optimized by the use of a multivariate strategy. Emphasis on the optimization study was given to the role of ionic strength, sugar concentration and pH of the donor sample solution prepared from the fruit samples. Since all three variables were found to affect negatively SDME (a lower extraction efficiency was observed as the values of variables were increased for most of the pesticides studied), donor sample solution was optimized using a central composite design to evaluate the optimum pH value and the optimum dilution of the sample extract. With some exceptions (chlorpyrifos ethyl, alpha-endosulfan, beta-endosulfan, pyriproxyfen, lambda-cyhalothrin and bifenthrin), the optimum method included the dilution of the analytical sample by 12.5-fold with a buffered acetone/water solution at pH=4 and exhibited good analytical characteristics for the majority of target analytes (pyrimethanil, pirimicarb, metribuzin, vinclozolin, fosthiazate, procymidone, fludioxonil, kresoxim methyl, endosulfan sulfate, fenhexamid, iprodione, phosalone, indoxacarb and azoxystrobin) by providing high enrichment factors (14-328), low limits of detection (0.0003-0.007 microg/g), and good precision (relative standard deviations below 15%).
PMID: 19783253

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