char = c;code = 99 char = i;code = 105 char = s;code = 115 char = -;code = 45 char = D;code = 68 char = i;code = 105 char = f;code = 102 char = l;code = 108 char = u;code = 117 char = o;code = 111 char = r;code = 114 char = i;code = 105 char = d;code = 100 char = o;code = 111 char = b;code = 98 char = i;code = 105 char = s;code = 115 char = (;code = 40 char = 1;code = 49 char = ,;code = 44 char = 1;code = 49 char = 0;code = 48 char = -;code = 45 char = p;code = 112 char = h;code = 104 char = e;code = 101 char = n;code = 110 char = a;code = 97 char = n;code = 110 char = t;code = 116 char = h;code = 104 char = r;code = 114 char = o;code = 111 char = l;code = 108 char = i;code = 105 char = n;code = 110 char = e;code = 101 char = );code = 41 char = c;code = 99 char = h;code = 104 char = r;code = 114 char = o;code = 111 char = m;code = 109 char = i;code = 105 char = u;code = 117 char = m;code = 109 char = (;code = 40 char = I;code = 73 char = I;code = 73 char = I;code = 73 char = );code = 41 char = ;code = 32 char = p;code = 112 char = e;code = 101 char = r;code = 114 char = c;code = 99 char = h;code = 104 char = l;code = 108 char = o;code = 111 char = r;code = 114 char = a;code = 97 char = t;code = 116 char = e;code = 101 char = ;code = 32 char = m;code = 109 char = o;code = 111 char = n;code = 110 char = o;code = 111 char = h;code = 104 char = y;code = 121 char = d;code = 100 char = r;code = 114 char = a;code = 97 char = t;code = 116 char = e;code = 101 char = .;code = 46 result sql = cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate.
cis-Difluoridobis(1,10-phenanthroline)chromium(III) perchlorate monohydrate.char = T;code = 84 char = h;code = 104 char = e;code = 101 char = ;code = 32 char = t;code = 116 char = i;code = 105 char = t;code = 116 char = l;code = 108 char = e;code = 101 char = ;code = 32 char = c;code = 99 char = o;code = 111 char = m;code = 109 char = p;code = 112 char = l;code = 108 char = e;code = 101 char = x;code = 120 char = ,;code = 44 char = ;code = 32 char = [;code = 91 char = C;code = 67 char = r;code = 114 char = F;code = 70 char = (;code = 40 char = 2;code = 50 char = );code = 41 char = (;code = 40 char = C;code = 67 char = (;code = 40 char = 1;code = 49 char = 2;code = 50 char = );code = 41 char = H;code = 72 char = (;code = 40 char = 8;code = 56 char = );code = 41 char = N;code = 78 char = (;code = 40 char = 2;code = 50 char = );code = 41 char = );code = 41 char = (;code = 40 char = 2;code = 50 char = );code = 41 char = ];code = 93 char = C;code = 67 char = l;code = 108 char = O;code = 79 char = (;code = 40 char = 4;code = 52 char = );code = 41 char = &;code = 38 char = #;code = 35 char = 1;code = 49 char = 8;code = 56 char = 3;code = 51 char = ;;code = 59 char = H;code = 72 char = (;code = 40 char = 2;code = 50 char = );code = 41 char = O;code = 79 char = ,;code = 44 char = ;code = 32 char = d;code = 100 char = i;code = 105 char = s;code = 115 char = p;code = 112 char = l;code = 108 char = a;code = 97 char = y;code = 121 char = s;code = 115 char = ;code = 32 char = a;code = 97 char = ;code = 32 char = s;code = 115 char = l;code = 108 char = i;code = 105 char = g;code = 103 char = h;code = 104 char = t;code = 116 char = l;code = 108 char = y;code = 121 char = ;code = 32 char = d;code = 100 char = i;code = 105 char = s;code = 115 char = t;code = 116 char = o;code = 111 char = r;code = 114 char = t;code = 116 char = e;code = 101 char = d;code = 100 char = ;code = 32 char = o;code = 111 char = c;code = 99 char = t;code = 116 char = a;code = 97 char = -;code = 45 char = h;code = 104 char = e;code = 101 char = d;code = 100 char = r;code = 114 char = a;code = 97 char = l;code = 108 char = ;code = 32 char = c;code = 99 char = o;code = 111 char = o;code = 111 char = r;code = 114 char = d;code = 100 char = i;code = 105 char = n;code = 110 char = a;code = 97 char = t;code = 116 char = i;code = 105 char = o;code = 111 char = n;code = 110 char = ;code = 32 char = g;code = 103 char = e;code = 101 char = o;code = 111 char = m;code = 109 char = e;code = 101 char = t;code = 116 char = r;code = 114 char = y;code = 121 char = ;code = 32 char = a;code = 97 char = r;code = 114 char = o;code = 111 char = u;code = 117 char = n;code = 110 char = d;code = 100 char = ;code = 32 char = t;code = 116 char = h;code = 104 char = e;code = 101 char = ;code = 32 char = c;code = 99 char = e;code = 101 char = n;code = 110 char = t;code = 116 char = r;code = 114 char = a;code = 97 char = l;code = 108 char = ;code = 32 char = c;code = 99 char = h;code = 104 char = r;code = 114 char = o;code = 111 char = m;code = 109 char = i;code = 105 char = u;code = 117 char = m;code = 109 char = (;code = 40 char = I;code = 73 char = I;code = 73 char = I;code = 73 char = );code = 41 char = ;code = 32 char = i;code = 105 char = o;code = 111 char = n;code = 110 char = .;code = 46 char = ;code = 32 char = T;code = 84 char = h;code = 104 char = e;code = 101 char = ;code = 32 char = C;code = 67 char = r;code = 114 char = ;code = 32 char = e;code = 101 char = n;code = 110 char = v;code = 118 char = i;code = 105 char = r;code = 114 char = o;code = 111 char = n;code = 110 char = m;code = 109 char = e;code = 101 char = n;code = 110 char = t;code = 116 char = ;code = 32 char = i;code = 105 char = s;code = 115 char = ;code = 32 char = c;code = 99 char = o;code = 111 char = m;code = 109 char = p;code = 112 char = o;code = 111 char = s;code = 115 char = e;code = 101 char = d;code = 100 char = ;code = 32 char = o;code = 111 char = f;code = 102 char = ;code = 32 char = a;code = 97 char = ;code = 32 char = c;code = 99 char = i;code = 105 char = s;code = 115 char = ;code = 32 char = a;code = 97 char = r;code = 114 char = r;code = 114 char = a;code = 97 char = n;code = 110 char = g;code = 103 char = e;code = 101 char = m;code = 109 char = e;code = 101 char = n;code = 110 char = t;code = 116 char = ;code = 32 char = o;code = 111 char = f;code = 102 char = ;code = 32 char = t;code = 116 char = w;code = 119 char = o;code = 111 char = ;code = 32 char = 1;code = 49 char = ,;code = 44 char = 1;code = 49 char = 0;code = 48 char = -;code = 45 char = p;code = 112 char = h;code = 104 char = e;code = 101 char = n;code = 110 char = a;code = 97 char = n;code = 110 char = t;code = 116 char = h;code = 104 char = r;code = 114 char = o;code = 111 char = l;code = 108 char = i;code = 105 char = n;code = 110 char = e;code = 101 char = ;code = 32 char = [;code = 91 char = a;code = 97 char = v;code = 118 char = e;code = 101 char = r;code = 114 char = a;code = 97 char = g;code = 103 char = e;code = 101 char = ;code = 32 char = C;code = 67 char = r;code = 114 char = (;code = 40 char = I;code = 73 char = I;code = 73 char = I;code = 73 char = );code = 41 char = -;code = 45 char = N;code = 78 char = ;code = 32 char = =;code = 61 char = ;code = 32 char = 2;code = 50 char = .;code = 46 char = 0;code = 48 char = 7;code = 55 char = 2;code = 50 char = 6;code = 54 char = &;code = 38 char = #;code = 35 char = 8;code = 56 char = 1;code = 49 char = 9;code = 57 char = 7;code = 55 char = ;;code = 59 char = (;code = 40 char = 1;code = 49 char = 0;code = 48 char = );code = 41 char = &;code = 38 char = #;code = 35 char = 8;code = 56 char = 1;code = 49 char = 9;code = 57 char = 7;code = 55 char = ;;code = 59 char = &;code = 38 char = #;code = 35 char = 1;code = 49 char = 9;code = 57 char = 7;code = 55 char = ;;code = 59 char = ];code = 93 char = ;code = 32 char = a;code = 97 char = n;code = 110 char = d;code = 100 char = ;code = 32 char = t;code = 116 char = w;code = 119 char = o;code = 111 char = ;code = 32 char = f;code = 102 char = l;code = 108 char = u;code = 117 char = o;code = 111 char = r;code = 114 char = i;code = 105 char = d;code = 100 char = e;code = 101 char = ;code = 32 char = [;code = 91 char = a;code = 97 char = v;code = 118 char = e;code = 101 char = r;code = 114 char = a;code = 97 char = g;code = 103 char = e;code = 101 char = ;code = 32 char = C;code = 67 char = r;code = 114 char = (;code = 40 char = I;code = 73 char = I;code = 73 char = I;code = 73 char = );code = 41 char = -;code = 45 char = F;code = 70 char = ;code = 32 char = =;code = 61 char = ;code = 32 char = 1;code = 49 char = .;code = 46 char = 8;code = 56 char = 5;code = 53 char = 3;code = 51 char = 3;code = 51 char = &;code = 38 char = #;code = 35 char = 8;code = 56 char = 1;code = 49 char = 9;code = 57 char = 7;code = 55 char = ;;code = 59 char = (;code = 40 char = 6;code = 54 char = );code = 41 char = &;code = 38 char = #;code = 35 char = 8;code = 56 char = 1;code = 49 char = 9;code = 57 char = 7;code = 55 char = ;;code = 59 char = &;code = 38 char = #;code = 35 char = 1;code = 49 char = 9;code = 57 char = 7;code = 55 char = ;;code = 59 char = ];code = 93 char = ;code = 32 char = l;code = 108 char = i;code = 105 char = g;code = 103 char = a;code = 97 char = n;code = 110 char = d;code = 100 char = s;code = 115 char = .;code = 46 char = ;code = 32 char = T;code = 84 char = h;code = 104 char = e;code = 101 char = ;code = 32 char = w;code = 119 char = a;code = 97 char = t;code = 116 char = e;code = 101 char = r;code = 114 char = ;code = 32 char = m;code = 109 char = o;code = 111 char = l;code = 108 char = e;code = 101 char = c;code = 99 char = u;code = 117 char = l;code = 108 char = e;code = 101 char = ;code = 32 char = f;code = 102 char = o;code = 111 char = r;code = 114 char = m;code = 109 char = s;code = 115 char = ;code = 32 char = a;code = 97 char = ;code = 32 char = h;code = 104 char = y;code = 121 char = d;code = 100 char = r;code = 114 char = o;code = 111 char = g;code = 103 char = e;code = 101 char = n;code = 110 char = ;code = 32 char = b;code = 98 char = o;code = 111 char = n;code = 110 char = d;code = 100 char = ;code = 32 char = t;code = 116 char = o;code = 111 char = ;code = 32 char = f;code = 102 char = l;code = 108 char = u;code = 117 char = o;code = 111 char = r;code = 114 char = i;code = 105 char = n;code = 110 char = e;code = 101 char = ;code = 32 char = i;code = 105 char = n;code = 110 char = ;code = 32 char = a;code = 97 char = ;code = 32 char = n;code = 110 char = e;code = 101 char = i;code = 105 char = g;code = 103 char = h;code = 104 char = b;code = 98 char = o;code = 111 char = u;code = 117 char = r;code = 114 char = i;code = 105 char = n;code = 110 char = g;code = 103 char = ;code = 32 char = c;code = 99 char = a;code = 97 char = t;code = 116 char = i;code = 105 char = o;code = 111 char = n;code = 110 char = .;code = 46 char = <;code = 60 char = b;code = 98 char = r;code = 114 char = /;code = 47 char = >;code = 62 result sql = The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa-hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)-N = 2.0726 (10) Å] and two fluoride [average Cr(III)-F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a neighbouring cation.
Publication: Acta Crystallogr Sect E Struct Rep Online 2008 ;64(Pt 2)::m369-70. :doi: 10.1107/S1600536808001153.
Publication Date: 2008
Study Author(s): Birk, Torben;Bendix, Jesper;Weihe, Högni;
Institution: Department of Chemistry, University of Copenhagen, Universitetsparken 5, DK-2100 København Ø, Denmark.
Shortcut link to this study:
The title complex, [CrF(2)(C(12)H(8)N(2))(2)]ClO(4)·H(2)O, displays a slightly distorted octa-hedral coordination geometry around the central chromium(III) ion. The Cr environment is composed of a cis arrangement of two 1,10-phenanthroline [average Cr(III)-N = 2.0726 (10) Å] and two fluoride [average Cr(III)-F = 1.8533 (6) Å] ligands. The water molecule forms a hydrogen bond to fluorine in a neighbouring cation.
PMID: 21201326