|
|
char = U;code = 85
char = V;code = 86
char = ;code = 32
char = s;code = 115
char = p;code = 112
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = s;code = 115
char = c;code = 99
char = o;code = 111
char = p;code = 112
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = );code = 41
char = ;code = 32
char = /;code = 47
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = O;code = 79
char = C;code = 67
char = l;code = 108
char = );code = 41
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = e;code = 101
char = q;code = 113
char = u;code = 117
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = u;code = 117
char = m;code = 109
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = t;code = 116
char = a;code = 97
char = n;code = 110
char = t;code = 116
char = .;code = 46
result sql = UV spectroscopic determination of the chlorine monoxide (ClO) / chlorine peroxide (ClOOCl) thermal equilibrium constant.
UV spectroscopic determination of the chlorine monoxide (ClO) / chlorine peroxide (ClOOCl) thermal equilibrium constant.char = T;code = 84
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = e;code = 101
char = q;code = 113
char = u;code = 117
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = u;code = 117
char = m;code = 109
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = t;code = 116
char = a;code = 97
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = t;code = 116
char = w;code = 119
char = e;code = 101
char = e;code = 101
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = r;code = 114
char = a;code = 97
char = d;code = 100
char = i;code = 105
char = c;code = 99
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = );code = 41
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = i;code = 105
char = t;code = 116
char = s;code = 115
char = ;code = 32
char = d;code = 100
char = i;code = 105
char = m;code = 109
char = e;code = 101
char = r;code = 114
char = ,;code = 44
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = O;code = 79
char = C;code = 67
char = l;code = 108
char = );code = 41
char = ,;code = 44
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = f;code = 102
char = u;code = 117
char = n;code = 110
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = e;code = 101
char = m;code = 109
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = t;code = 116
char = w;code = 119
char = e;code = 101
char = e;code = 101
char = n;code = 110
char = ;code = 32
char = 2;code = 50
char = 2;code = 50
char = 8;code = 56
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = 3;code = 51
char = 0;code = 48
char = 1;code = 49
char = K;code = 75
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = d;code = 100
char = i;code = 105
char = s;code = 115
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = r;code = 114
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = f;code = 102
char = l;code = 108
char = o;code = 111
char = w;code = 119
char = ;code = 32
char = a;code = 97
char = p;code = 112
char = p;code = 112
char = a;code = 97
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = u;code = 117
char = s;code = 115
char = ;code = 32
char = u;code = 117
char = s;code = 115
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = b;code = 98
char = r;code = 114
char = o;code = 111
char = a;code = 97
char = d;code = 100
char = b;code = 98
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = U;code = 85
char = V;code = 86
char = ;code = 32
char = a;code = 97
char = b;code = 98
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = s;code = 115
char = p;code = 112
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = s;code = 115
char = c;code = 99
char = o;code = 111
char = p;code = 112
char = y;code = 121
char = .;code = 46
char = ;code = 32
char = A;code = 65
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = r;code = 114
char = d;code = 100
char = -;code = 45
char = l;code = 108
char = a;code = 97
char = w;code = 119
char = ;code = 32
char = f;code = 102
char = i;code = 105
char = t;code = 116
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = q;code = 113
char = u;code = 117
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = u;code = 117
char = m;code = 109
char = ;code = 32
char = v;code = 118
char = a;code = 97
char = l;code = 108
char = u;code = 117
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = f;code = 102
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = i;code = 105
char = m;code = 109
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = d;code = 100
char = a;code = 97
char = t;code = 116
char = a;code = 97
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = o;code = 111
char = v;code = 118
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = p;code = 112
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = s;code = 115
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = <;code = 60
char = i;code = 105
char = >;code = 62
char = K;code = 75
char = <;code = 60
char = /;code = 47
char = i;code = 105
char = >;code = 62
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = >;code = 62
char = e;code = 101
char = q;code = 113
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 2;code = 50
char = .;code = 46
char = 1;code = 49
char = 6;code = 54
char = ;code = 32
char = ×;code = 215
char = ;code = 32
char = 1;code = 49
char = 0;code = 48
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = -;code = 45
char = 2;code = 50
char = 7;code = 55
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = <;code = 60
char = i;code = 105
char = >;code = 62
char = e;code = 101
char = <;code = 60
char = /;code = 47
char = i;code = 105
char = >;code = 62
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = (;code = 40
char = 8;code = 56
char = 5;code = 53
char = 2;code = 50
char = 7;code = 55
char = ±;code = 177
char = 3;code = 51
char = 5;code = 53
char = ;code = 32
char = K;code = 75
char = /;code = 47
char = <;code = 60
char = i;code = 105
char = >;code = 62
char = T;code = 84
char = <;code = 60
char = /;code = 47
char = i;code = 105
char = >;code = 62
char = );code = 41
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = ;code = 32
char = c;code = 99
char = m;code = 109
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = 3;code = 51
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = e;code = 101
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = -;code = 45
char = 1;code = 49
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = ;code = 32
char = (;code = 40
char = 1;code = 49
char = σ;code = 963
char = ;code = 32
char = u;code = 117
char = n;code = 110
char = c;code = 99
char = e;code = 101
char = r;code = 114
char = t;code = 116
char = a;code = 97
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = y;code = 121
char = );code = 41
char = .;code = 46
char = ;code = 32
char = A;code = 65
char = ;code = 32
char = s;code = 115
char = e;code = 101
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = -;code = 45
char = l;code = 108
char = a;code = 97
char = w;code = 119
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = y;code = 121
char = s;code = 115
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = d;code = 100
char = a;code = 97
char = t;code = 116
char = a;code = 97
char = ;code = 32
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = o;code = 111
char = d;code = 100
char = ;code = 32
char = a;code = 97
char = g;code = 103
char = r;code = 114
char = e;code = 101
char = e;code = 101
char = m;code = 109
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = .;code = 46
char = ;code = 32
char = F;code = 70
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = l;code = 108
char = o;code = 111
char = p;code = 112
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = v;code = 118
char = a;code = 97
char = n;code = 110
char = ';code = 39
char = t;code = 116
char = ;code = 32
char = H;code = 72
char = o;code = 111
char = f;code = 102
char = f;code = 102
char = ;code = 32
char = p;code = 112
char = l;code = 108
char = o;code = 111
char = t;code = 116
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = r;code = 114
char = d;code = 100
char = -;code = 45
char = l;code = 108
char = a;code = 97
char = w;code = 119
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = y;code = 121
char = s;code = 115
char = i;code = 105
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = l;code = 108
char = p;code = 112
char = y;code = 121
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = ;code = 32
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = O;code = 79
char = C;code = 67
char = l;code = 108
char = ;code = 32
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = l;code = 108
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = d;code = 100
char = ,;code = 44
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = a;code = 97
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = x;code = 120
char = m;code = 109
char = l;code = 108
char = n;code = 110
char = s;code = 115
char = :;code = 58
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = =;code = 61
char = ";code = 34
char = h;code = 104
char = t;code = 116
char = t;code = 116
char = p;code = 112
char = :;code = 58
char = /;code = 47
char = /;code = 47
char = w;code = 119
char = w;code = 119
char = w;code = 119
char = .;code = 46
char = w;code = 119
char = 3;code = 51
char = .;code = 46
char = o;code = 111
char = r;code = 114
char = g;code = 103
char = /;code = 47
char = 1;code = 49
char = 9;code = 57
char = 9;code = 57
char = 8;code = 56
char = /;code = 47
char = M;code = 77
char = a;code = 97
char = t;code = 116
char = h;code = 104
char = /;code = 47
char = M;code = 77
char = a;code = 97
char = t;code = 116
char = h;code = 104
char = M;code = 77
char = L;code = 76
char = ";code = 34
char = >;code = 62
char =
;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = r;code = 114
char = o;code = 111
char = w;code = 119
char = >;code = 62
char =
;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
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char = u;code = 117
char = b;code = 98
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char = u;code = 117
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char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
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;code = 10
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char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
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char = ;code = 32
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char = m;code = 109
char = l;code = 108
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char = m;code = 109
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char = Δ;code = 916
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char = m;code = 109
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char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
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char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = i;code = 105
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char = H;code = 72
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = i;code = 105
char = >;code = 62
char =
;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = r;code = 114
char = o;code = 111
char = w;code = 119
char = >;code = 62
char =
;code = 10
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char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = t;code = 116
char = e;code = 101
char = x;code = 120
char = t;code = 116
char = >;code = 62
char = f;code = 102
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = t;code = 116
char = e;code = 101
char = x;code = 120
char = t;code = 116
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char =
;code = 10
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char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = o;code = 111
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char = °;code = 176
char = <;code = 60
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char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = o;code = 111
char = >;code = 62
char =
;code = 10
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char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char =
;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = r;code = 114
char = o;code = 111
char = w;code = 119
char = >;code = 62
char =
;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = a;code = 97
char = t;code = 116
char = h;code = 104
char = >;code = 62
char = ;code = 32
char = (;code = 40
char = 2;code = 50
char = 9;code = 57
char = 8;code = 56
char = ;code = 32
char = K;code = 75
char = );code = 41
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 1;code = 49
char = 3;code = 51
char = 0;code = 48
char = .;code = 46
char = 0;code = 48
char = ;code = 32
char = ±;code = 177
char = ;code = 32
char = 0;code = 48
char = .;code = 46
char = 6;code = 54
char = ;code = 32
char = k;code = 107
char = J;code = 74
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = l;code = 108
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = -;code = 45
char = 1;code = 49
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = .;code = 46
char = ;code = 32
char = T;code = 84
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = q;code = 113
char = u;code = 117
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = u;code = 117
char = m;code = 109
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = t;code = 116
char = a;code = 97
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = u;code = 117
char = l;code = 108
char = t;code = 116
char = s;code = 115
char = ;code = 32
char = f;code = 102
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = u;code = 117
char = d;code = 100
char = y;code = 121
char = ;code = 32
char = s;code = 115
char = u;code = 117
char = g;code = 103
char = g;code = 103
char = e;code = 101
char = s;code = 115
char = t;code = 116
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = t;code = 116
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = u;code = 117
char = n;code = 110
char = c;code = 99
char = e;code = 101
char = r;code = 114
char = t;code = 116
char = a;code = 97
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = i;code = 105
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = i;code = 105
char = n;code = 110
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char = <;code = 60
char = i;code = 105
char = >;code = 62
char = K;code = 75
char = <;code = 60
char = /;code = 47
char = i;code = 105
char = >;code = 62
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = >;code = 62
char = e;code = 101
char = q;code = 113
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = c;code = 99
char = o;code = 111
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char = m;code = 109
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char = d;code = 100
char = e;code = 101
char = d;code = 100
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char = h;code = 104
char = e;code = 101
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char = ;code = 32
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char = e;code = 101
char = c;code = 99
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = ;code = 32
char = (;code = 40
char = y;code = 121
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = 2;code = 50
char = 0;code = 48
char = 1;code = 49
char = 5;code = 53
char = );code = 41
char = ;code = 32
char = N;code = 78
char = A;code = 65
char = S;code = 83
char = A;code = 65
char = ;code = 32
char = J;code = 74
char = P;code = 80
char = L;code = 76
char = ;code = 32
char = D;code = 68
char = a;code = 97
char = t;code = 116
char = a;code = 97
char = ;code = 32
char = E;code = 69
char = v;code = 118
char = a;code = 97
char = l;code = 108
char = u;code = 117
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = n;code = 110
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = i;code = 105
char = g;code = 103
char = n;code = 110
char = i;code = 105
char = f;code = 102
char = i;code = 105
char = c;code = 99
char = a;code = 97
char = n;code = 110
char = t;code = 116
char = l;code = 108
char = y;code = 121
char = ;code = 32
char = r;code = 114
char = e;code = 101
char = d;code = 100
char = u;code = 117
char = c;code = 99
char = e;code = 101
char = d;code = 100
char = .;code = 46
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = >;code = 62
char = <;code = 60
char = b;code = 98
char = r;code = 114
char = >;code = 62
result sql = The thermal equilibrium constant between the chlorine monoxide radical (ClO) and its dimer, chlorine peroxide (ClOOCl), was determined as a function of temperature between 228 and 301K in a discharge flow apparatus using broadband UV absorption spectroscopy. A third-law fit of the equilibrium values determined from the experimental data provides the expression Keq = 2.16 × 10-27e(8527±35 K/T) cm3 molecule-1 (1σ uncertainty). A second-law analysis of the data is in good agreement. From the slope of the van't Hoff plot in the third-law analysis, the enthalpy of formation for ClOOCl is calculated,
Δ
H
f
°
(298 K) = 130.0 ± 0.6 kJ mol-1. The equilibrium constant results from this study suggest that the uncertainties in Keq recommended in the most recent (year 2015) NASA JPL Data Evaluation can be significantly reduced.
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char = s;code = 115
char = p;code = 112
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = s;code = 115
char = c;code = 99
char = o;code = 111
char = p;code = 112
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = );code = 41
char = ;code = 32
char = /;code = 47
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = l;code = 108
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = O;code = 79
char = C;code = 67
char = l;code = 108
char = );code = 41
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = e;code = 101
char = q;code = 113
char = u;code = 117
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = u;code = 117
char = m;code = 109
char = ;code = 32
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = s;code = 115
char = t;code = 116
char = a;code = 97
char = n;code = 110
char = t;code = 116
char = .;code = 46
result sql = UV spectroscopic determination of the chlorine monoxide (ClO) / chlorine peroxide (ClOOCl) thermal equilibrium constant.
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char = ;code = 32
char = t;code = 116
char = h;code = 104
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char = l;code = 108
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char = e;code = 101
char = q;code = 113
char = u;code = 117
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = b;code = 98
char = r;code = 114
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char = u;code = 117
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char = s;code = 115
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char = e;code = 101
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char = ;code = 32
char = c;code = 99
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char = l;code = 108
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char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
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char = o;code = 111
char = x;code = 120
char = i;code = 105
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char = l;code = 108
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char = l;code = 108
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char = ;code = 32
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char = d;code = 100
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char = m;code = 109
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char = r;code = 114
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char = l;code = 108
char = o;code = 111
char = r;code = 114
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = ;code = 32
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char = e;code = 101
char = r;code = 114
char = o;code = 111
char = x;code = 120
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = ;code = 32
char = (;code = 40
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = O;code = 79
char = C;code = 67
char = l;code = 108
char = );code = 41
char = ,;code = 44
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = f;code = 102
char = u;code = 117
char = n;code = 110
char = c;code = 99
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = e;code = 101
char = m;code = 109
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = u;code = 117
char = r;code = 114
char = e;code = 101
char = ;code = 32
char = b;code = 98
char = e;code = 101
char = t;code = 116
char = w;code = 119
char = e;code = 101
char = e;code = 101
char = n;code = 110
char = ;code = 32
char = 2;code = 50
char = 2;code = 50
char = 8;code = 56
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = 3;code = 51
char = 0;code = 48
char = 1;code = 49
char = K;code = 75
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = d;code = 100
char = i;code = 105
char = s;code = 115
char = c;code = 99
char = h;code = 104
char = a;code = 97
char = r;code = 114
char = g;code = 103
char = e;code = 101
char = ;code = 32
char = f;code = 102
char = l;code = 108
char = o;code = 111
char = w;code = 119
char = ;code = 32
char = a;code = 97
char = p;code = 112
char = p;code = 112
char = a;code = 97
char = r;code = 114
char = a;code = 97
char = t;code = 116
char = u;code = 117
char = s;code = 115
char = ;code = 32
char = u;code = 117
char = s;code = 115
char = i;code = 105
char = n;code = 110
char = g;code = 103
char = ;code = 32
char = b;code = 98
char = r;code = 114
char = o;code = 111
char = a;code = 97
char = d;code = 100
char = b;code = 98
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = U;code = 85
char = V;code = 86
char = ;code = 32
char = a;code = 97
char = b;code = 98
char = s;code = 115
char = o;code = 111
char = r;code = 114
char = p;code = 112
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = s;code = 115
char = p;code = 112
char = e;code = 101
char = c;code = 99
char = t;code = 116
char = r;code = 114
char = o;code = 111
char = s;code = 115
char = c;code = 99
char = o;code = 111
char = p;code = 112
char = y;code = 121
char = .;code = 46
char = ;code = 32
char = A;code = 65
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = r;code = 114
char = d;code = 100
char = -;code = 45
char = l;code = 108
char = a;code = 97
char = w;code = 119
char = ;code = 32
char = f;code = 102
char = i;code = 105
char = t;code = 116
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = q;code = 113
char = u;code = 117
char = i;code = 105
char = l;code = 108
char = i;code = 105
char = b;code = 98
char = r;code = 114
char = i;code = 105
char = u;code = 117
char = m;code = 109
char = ;code = 32
char = v;code = 118
char = a;code = 97
char = l;code = 108
char = u;code = 117
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = d;code = 100
char = e;code = 101
char = t;code = 116
char = e;code = 101
char = r;code = 114
char = m;code = 109
char = i;code = 105
char = n;code = 110
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = f;code = 102
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = p;code = 112
char = e;code = 101
char = r;code = 114
char = i;code = 105
char = m;code = 109
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = a;code = 97
char = l;code = 108
char = ;code = 32
char = d;code = 100
char = a;code = 97
char = t;code = 116
char = a;code = 97
char = ;code = 32
char = p;code = 112
char = r;code = 114
char = o;code = 111
char = v;code = 118
char = i;code = 105
char = d;code = 100
char = e;code = 101
char = s;code = 115
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = x;code = 120
char = p;code = 112
char = r;code = 114
char = e;code = 101
char = s;code = 115
char = s;code = 115
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = <;code = 60
char = i;code = 105
char = >;code = 62
char = K;code = 75
char = <;code = 60
char = /;code = 47
char = i;code = 105
char = >;code = 62
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = >;code = 62
char = e;code = 101
char = q;code = 113
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = >;code = 62
char = ;code = 32
char = =;code = 61
char = ;code = 32
char = 2;code = 50
char = .;code = 46
char = 1;code = 49
char = 6;code = 54
char = ;code = 32
char = ×;code = 215
char = ;code = 32
char = 1;code = 49
char = 0;code = 48
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = -;code = 45
char = 2;code = 50
char = 7;code = 55
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = <;code = 60
char = i;code = 105
char = >;code = 62
char = e;code = 101
char = <;code = 60
char = /;code = 47
char = i;code = 105
char = >;code = 62
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = (;code = 40
char = 8;code = 56
char = 5;code = 53
char = 2;code = 50
char = 7;code = 55
char = ±;code = 177
char = 3;code = 51
char = 5;code = 53
char = ;code = 32
char = K;code = 75
char = /;code = 47
char = <;code = 60
char = i;code = 105
char = >;code = 62
char = T;code = 84
char = <;code = 60
char = /;code = 47
char = i;code = 105
char = >;code = 62
char = );code = 41
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = ;code = 32
char = c;code = 99
char = m;code = 109
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = 3;code = 51
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = l;code = 108
char = e;code = 101
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = e;code = 101
char = <;code = 60
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = -;code = 45
char = 1;code = 49
char = <;code = 60
char = /;code = 47
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = ;code = 32
char = (;code = 40
char = 1;code = 49
char = σ;code = 963
char = ;code = 32
char = u;code = 117
char = n;code = 110
char = c;code = 99
char = e;code = 101
char = r;code = 114
char = t;code = 116
char = a;code = 97
char = i;code = 105
char = n;code = 110
char = t;code = 116
char = y;code = 121
char = );code = 41
char = .;code = 46
char = ;code = 32
char = A;code = 65
char = ;code = 32
char = s;code = 115
char = e;code = 101
char = c;code = 99
char = o;code = 111
char = n;code = 110
char = d;code = 100
char = -;code = 45
char = l;code = 108
char = a;code = 97
char = w;code = 119
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = y;code = 121
char = s;code = 115
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = d;code = 100
char = a;code = 97
char = t;code = 116
char = a;code = 97
char = ;code = 32
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = g;code = 103
char = o;code = 111
char = o;code = 111
char = d;code = 100
char = ;code = 32
char = a;code = 97
char = g;code = 103
char = r;code = 114
char = e;code = 101
char = e;code = 101
char = m;code = 109
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = .;code = 46
char = ;code = 32
char = F;code = 70
char = r;code = 114
char = o;code = 111
char = m;code = 109
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = l;code = 108
char = o;code = 111
char = p;code = 112
char = e;code = 101
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = v;code = 118
char = a;code = 97
char = n;code = 110
char = ';code = 39
char = t;code = 116
char = ;code = 32
char = H;code = 72
char = o;code = 111
char = f;code = 102
char = f;code = 102
char = ;code = 32
char = p;code = 112
char = l;code = 108
char = o;code = 111
char = t;code = 116
char = ;code = 32
char = i;code = 105
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = i;code = 105
char = r;code = 114
char = d;code = 100
char = -;code = 45
char = l;code = 108
char = a;code = 97
char = w;code = 119
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = a;code = 97
char = l;code = 108
char = y;code = 121
char = s;code = 115
char = i;code = 105
char = s;code = 115
char = ,;code = 44
char = ;code = 32
char = t;code = 116
char = h;code = 104
char = e;code = 101
char = ;code = 32
char = e;code = 101
char = n;code = 110
char = t;code = 116
char = h;code = 104
char = a;code = 97
char = l;code = 108
char = p;code = 112
char = y;code = 121
char = ;code = 32
char = o;code = 111
char = f;code = 102
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = ;code = 32
char = C;code = 67
char = l;code = 108
char = O;code = 79
char = O;code = 79
char = C;code = 67
char = l;code = 108
char = ;code = 32
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = c;code = 99
char = a;code = 97
char = l;code = 108
char = c;code = 99
char = u;code = 117
char = l;code = 108
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = d;code = 100
char = ,;code = 44
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = a;code = 97
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = x;code = 120
char = m;code = 109
char = l;code = 108
char = n;code = 110
char = s;code = 115
char = :;code = 58
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = =;code = 61
char = ";code = 34
char = h;code = 104
char = t;code = 116
char = t;code = 116
char = p;code = 112
char = :;code = 58
char = /;code = 47
char = /;code = 47
char = w;code = 119
char = w;code = 119
char = w;code = 119
char = .;code = 46
char = w;code = 119
char = 3;code = 51
char = .;code = 46
char = o;code = 111
char = r;code = 114
char = g;code = 103
char = /;code = 47
char = 1;code = 49
char = 9;code = 57
char = 9;code = 57
char = 8;code = 56
char = /;code = 47
char = M;code = 77
char = a;code = 97
char = t;code = 116
char = h;code = 104
char = /;code = 47
char = M;code = 77
char = a;code = 97
char = t;code = 116
char = h;code = 104
char = M;code = 77
char = L;code = 76
char = ";code = 34
char = >;code = 62
char = ;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = r;code = 114
char = o;code = 111
char = w;code = 119
char = >;code = 62
char = ;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = s;code = 115
char = u;code = 117
char = b;code = 98
char = s;code = 115
char = u;code = 117
char = p;code = 112
char = >;code = 62
char = ;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = r;code = 114
char = o;code = 111
char = w;code = 119
char = >;code = 62
char = ;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = i;code = 105
char = >;code = 62
char = Δ;code = 916
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = i;code = 105
char = >;code = 62
char = ;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = i;code = 105
char = >;code = 62
char = H;code = 72
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = i;code = 105
char = >;code = 62
char = ;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = r;code = 114
char = o;code = 111
char = w;code = 119
char = >;code = 62
char = ;code = 10
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = ;code = 32
char = <;code = 60
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = t;code = 116
char = e;code = 101
char = x;code = 120
char = t;code = 116
char = >;code = 62
char = f;code = 102
char = <;code = 60
char = /;code = 47
char = m;code = 109
char = m;code = 109
char = l;code = 108
char = :;code = 58
char = m;code = 109
char = t;code = 116
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char = h;code = 104
char = e;code = 101
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char = e;code = 101
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char = e;code = 101
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char = ;code = 32
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char = ;code = 32
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char = t;code = 116
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char = o;code = 111
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char = ;code = 32
char = c;code = 99
char = a;code = 97
char = n;code = 110
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char = b;code = 98
char = e;code = 101
char = ;code = 32
char = s;code = 115
char = i;code = 105
char = g;code = 103
char = n;code = 110
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char = i;code = 105
char = c;code = 99
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char = n;code = 110
char = t;code = 116
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char = y;code = 121
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char = d;code = 100
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result sql = The thermal equilibrium constant between the chlorine monoxide radical (ClO) and its dimer, chlorine peroxide (ClOOCl), was determined as a function of temperature between 228 and 301K in a discharge flow apparatus using broadband UV absorption spectroscopy. A third-law fit of the equilibrium values determined from the experimental data provides the expression Keq = 2.16 × 10-27e(8527±35 K/T) cm3 molecule-1 (1σ uncertainty). A second-law analysis of the data is in good agreement. From the slope of the van't Hoff plot in the third-law analysis, the enthalpy of formation for ClOOCl is calculated,
Publication: Atmos Chem Phys 2019 May;19(9):6205-6215.
Publication Date: May 2019
Study Author(s): Klobas J Eric JE ; Wilmouth David M DM ;
Institution: Harvard John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA.
Shortcut link to this study:
Publication Date: May 2019
Study Author(s): Klobas J Eric JE ; Wilmouth David M DM ;
Institution: Harvard John A. Paulson School of Engineering and Applied Sciences, Harvard University, Cambridge, MA 02138, USA.
Shortcut link to this study:
The thermal equilibrium constant between the chlorine monoxide radical (ClO) and its dimer, chlorine peroxide (ClOOCl), was determined as a function of temperature between 228 and 301K in a discharge flow apparatus using broadband UV absorption spectroscopy. A third-law fit of the equilibrium values determined from the experimental data provides the expression Keq = 2.16 × 10-27e(8527±35 K/T) cm3 molecule-1 (1σ uncertainty). A second-law analysis of the data is in good agreement. From the slope of the van't Hoff plot in the third-law analysis, the enthalpy of formation for ClOOCl is calculated,
Δ
H
f
°
(298 K) = 130.0 ± 0.6 kJ mol-1. The equilibrium constant results from this study suggest that the uncertainties in Keq recommended in the most recent (year 2015) NASA JPL Data Evaluation can be significantly reduced.
PMID: 31632449
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