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Studies on the chelation of aluminum for neurobiological application.
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char = E;code = 69
char = D;code = 68
char = T;code = 84
char = A;code = 65
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char = (;code = 40
char = 1;code = 49
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char = 1;code = 49
char = );code = 41
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = e;code = 101
char = l;code = 108
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = w;code = 119
char = a;code = 97
char = s;code = 115
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = u;code = 117
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = t;code = 116
char = o;code = 111
char = ;code = 32
char = u;code = 117
char = n;code = 110
char = d;code = 100
char = e;code = 101
char = r;code = 114
char = g;code = 103
char = o;code = 111
char = ;code = 32
char = h;code = 104
char = y;code = 121
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = l;code = 108
char = y;code = 121
char = s;code = 115
char = i;code = 105
char = s;code = 115
char = ;code = 32
char = e;code = 101
char = v;code = 118
char = e;code = 101
char = n;code = 110
char = ;code = 32
char = a;code = 97
char = t;code = 116
char = ;code = 32
char = p;code = 112
char = H;code = 72
char = ;code = 32
char = 5;code = 53
char = .;code = 46
char = ;code = 32
char = H;code = 72
char = o;code = 111
char = w;code = 119
char = e;code = 101
char = v;code = 118
char = e;code = 101
char = r;code = 114
char = ,;code = 44
char = ;code = 32
char = E;code = 69
char = D;code = 68
char = D;code = 68
char = H;code = 72
char = A;code = 65
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = H;code = 72
char = B;code = 66
char = E;code = 69
char = D;code = 68
char = ;code = 32
char = e;code = 101
char = a;code = 97
char = c;code = 99
char = h;code = 104
char = ;code = 32
char = f;code = 102
char = o;code = 111
char = r;code = 114
char = m;code = 109
char = e;code = 101
char = d;code = 100
char = ;code = 32
char = a;code = 97
char = ;code = 32
char = v;code = 118
char = e;code = 101
char = r;code = 114
char = y;code = 121
char = ;code = 32
char = s;code = 115
char = t;code = 116
char = a;code = 97
char = b;code = 98
char = l;code = 108
char = e;code = 101
char = ;code = 32
char = m;code = 109
char = o;code = 111
char = n;code = 110
char = o;code = 111
char = n;code = 110
char = u;code = 117
char = c;code = 99
char = l;code = 108
char = e;code = 101
char = a;code = 97
char = r;code = 114
char = ;code = 32
char = c;code = 99
char = h;code = 104
char = e;code = 101
char = l;code = 108
char = a;code = 97
char = t;code = 116
char = e;code = 101
char = ;code = 32
char = w;code = 119
char = i;code = 105
char = t;code = 116
char = h;code = 104
char = ;code = 32
char = A;code = 65
char = 1;code = 49
char = (;code = 40
char = I;code = 73
char = I;code = 73
char = I;code = 73
char = );code = 41
char = ;code = 32
char = a;code = 97
char = n;code = 110
char = d;code = 100
char = ;code = 32
char = d;code = 100
char = i;code = 105
char = d;code = 100
char = ;code = 32
char = n;code = 110
char = o;code = 111
char = t;code = 116
char = ;code = 32
char = s;code = 115
char = h;code = 104
char = o;code = 111
char = w;code = 119
char = ;code = 32
char = h;code = 104
char = y;code = 121
char = d;code = 100
char = r;code = 114
char = o;code = 111
char = l;code = 108
char = y;code = 121
char = t;code = 116
char = i;code = 105
char = c;code = 99
char = ;code = 32
char = o;code = 111
char = r;code = 114
char = ;code = 32
char = p;code = 112
char = o;code = 111
char = l;code = 108
char = y;code = 121
char = m;code = 109
char = e;code = 101
char = r;code = 114
char = i;code = 105
char = z;code = 122
char = a;code = 97
char = t;code = 116
char = i;code = 105
char = o;code = 111
char = n;code = 110
char = ;code = 32
char = t;code = 116
char = e;code = 101
char = n;code = 110
char = d;code = 100
char = e;code = 101
char = n;code = 110
char = c;code = 99
char = i;code = 105
char = e;code = 101
char = s;code = 115
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char = <;code = 60
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char = >;code = 62
result sql = The formation and strength of chelation of A1(III) with salicylic acid (SA), citric acid (CIT), ethylenediaminetetraacetic acid (EDTA), ethylenediamine-di-(o-hydroxyphenylacetic acid) (EDDHA), N,N'-di-(2-hydroxybenzyl)ethylenediamine-N,N'-diacetic acid (HBED), and some mixed ligand systems consisting of the above ligands were examined at an ionic strength of 0.12 M NaCl and 25.0 +/- 0.1 degrees C. All the ligands under consideration form strong chelates with A1(III). The order of the stabilities (log KML) of their A1(III) chelates are SA (13.7) less than EDTA (15.3) less than CIT (18.0) less than EDDHA (24.5) approximately equal to HBED (24.8). An equilibrium analysis of the A1(III)-SA (1:1), A1(III)-CIT (1:1) and A1(III)-SA-CIT (1:1:1) systems indicated the occurrence of hydrolysis and polymerization reactions in each one of them. The A1(III)-EDTA (1:1) chelate was found to undergo hydrolysis even at pH 5. However, EDDHA and HBED each formed a very stable mononuclear chelate with A1(III) and did not show hydrolytic or polymerization tendencies.

Publication: J. Inorg. Biochem. 1981 Jul ;14(4)::339-50.
Publication Date: 1981 Jul
Study Author(s): Rajan, K S;Mainer, S;Rajan, N L;Davis, J M;
Institution:
Shortcut link to this study:

The formation and strength of chelation of A1(III) with salicylic acid (SA), citric acid (CIT), ethylenediaminetetraacetic acid (EDTA), ethylenediamine-di-(o-hydroxyphenylacetic acid) (EDDHA), N,N'-di-(2-hydroxybenzyl)ethylenediamine-N,N'-diacetic acid (HBED), and some mixed ligand systems consisting of the above ligands were examined at an ionic strength of 0.12 M NaCl and 25.0 +/- 0.1 degrees C. All the ligands under consideration form strong chelates with A1(III). The order of the stabilities (log KML) of their A1(III) chelates are SA (13.7) less than EDTA (15.3) less than CIT (18.0) less than EDDHA (24.5) approximately equal to HBED (24.8). An equilibrium analysis of the A1(III)-SA (1:1), A1(III)-CIT (1:1) and A1(III)-SA-CIT (1:1:1) systems indicated the occurrence of hydrolysis and polymerization reactions in each one of them. The A1(III)-EDTA (1:1) chelate was found to undergo hydrolysis even at pH 5. However, EDDHA and HBED each formed a very stable mononuclear chelate with A1(III) and did not show hydrolytic or polymerization tendencies.

PMID: 7276932

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